Effect of the "host-guest" interactions on the low frequency vibrational dynamics of Gen/beta-CyD and Gen/SBE-beta-CyD inclusion complexes

DOI

Complexation is of interest in pharmaceutical field, since it increases solubility and bioavailabilityof drugs. We want to perform a inelastic neutron scattering (INS) study, vs. T, of the vibrational dynamics of the inclusion complexes of beta-Cyclodextrin (beta-CyD) and its derivative sulfobutylether-beta-Cyclodextrin (SBE-beta-CyD) with Genistein, an antioxidant phytoestrogen, compared to single components and physical mixtures. The aim is to examine if and how the dynamics of the complexes in the ps-ns timescale is affected by the host-guest interactions, and to probe if there exists a relationship of this dynamics with the stability. The comparative analysis of will also allow to test the access offered by these two macrocycles to Genistein. The results are relevant to tailor the release of drugs with specific properties.

Identifier
DOI https://doi.org/10.5286/ISIS.E.67771490
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/67771490
Provenance
Creator Miss Cettina Bottari; Professor Vincenza Crupi; Professor Valentina Venuti; Professor Ines Mancini; Professor Domenico Majolino; Dr Alessandro Paciaroni; Professor Graziano Guella; Dr Ian Silverwood; Dr Barbara Rossi; Dr Rosanna Stancanelli
Publisher ISIS Neutron and Muon Source
Publication Year 2018
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Biology; Biomaterials; Engineering Sciences; Life Sciences; Materials Science; Materials Science and Engineering; Natural Sciences; Physics
Temporal Coverage Begin 2015-11-26T09:00:00Z
Temporal Coverage End 2015-12-01T09:00:00Z