The data set contains mineral chemical analyses of 37 different surface materials from the copper-gold-pyrite mine Apliki in the Republic of Cyprus and their corresponding hyperspectral spectra. The field samples were sampled in March 2018 in cooperation of the Cyprus Geological Survey Department of the Republic of Cyprus (GSD) and the German Research Centre for Geosciences (GFZ). The hyperspectral data was acquired with the HySpex system in a range of 400 – 2500nm and is presented in a spectral library. Detailed information about the mineral specimen, sample area and geochemistry is presented in the data sheets. The spectral library presented here is part of a bigger collection of spectral libraries including samples from rare-earth minerals, rare-earth-oxides (Koerting et al., 2019a, http://doi.org/10.5880/GFZ.1.4.2019.004) and copper-bearing minerals (Koellner et al., 2019, http://doi.org/10.5880/GFZ.1.4.2019.003).