Experimental Data to the publication "Understanding Structure-Activity Relationships: Iron(II) Complexes of “Legacy Guanidines” as Catalysts for the Synthesis of Polylactide"


NMR spectroscopic data, GPC data, DSC data and Raman spectroscopic data for the ring-opening polymerisation of lactide and depolymerisation of polylactide of a series of non toxic Fe catalyst were deposited.

Bruker Avance II (400MHz)

Bruker Avance III (400MHz)

Bruker Avance Neo (400MHz)

GPCmax VE-2001 from Viscotek: two Malvern Viscotek T columns (porous styrene divinylbenzene copolymer) with a maximum pore size of 500 and 5000Å, a refractive index detector (VE-3580), and a viscometer (Viscotek 270 Dual Detector)

Netzsch DSC 204 F1 Phoenix equipped with an intra-cooler

RXN1 spectrometer of Kaiser Optical System with a 785nm laser

Bruker ultrafleXtreme equipped with a 337 nm smart beam laser in the reflective mode was used. The protein mixture Protein 1 calibration standard was used for calibration. For the spectra, 4000 laser shots with 24% laser power were collected. The laser repetition rate was 1000 Hz.

DOI https://doi.org/10.22000/1625
Related Identifier https://doi.org/10.1039/D3CY01117H
Metadata Access https://www.radar-service.eu/oai/OAIHandler?verb=GetRecord&metadataPrefix=datacite&identifier=10.22000/1625
Creator Conrads, Christian ORCID logo; Burkart, Lisa; Soerensen, Sven; Noichl, Sandra; Kara, Yasemin; Heck, Joshua ORCID logo; Hoffmann, Alexander ORCID logo; Herres-Pawlis, Sonja ORCID logo
Publisher RWTH Aachen University
Contributor RADAR
Publication Year 2023
Funding Reference European Commission 501100000780 Crossref Funder ID H2020: 953073 https://cordis.europa.eu/project/id/953073 sUstainable PLastIcs for the Food and drink packaging indusTry (UPLIFT)
Rights Open Access; Creative Commons Attribution Non Commercial Share Alike 4.0 International; info:eu-repo/semantics/openAccess; https://creativecommons.org/licenses/by-nc-sa/4.0/legalcode
OpenAccess true
Language English
Resource Type NMR, GPC, DSC and Raman spectroscopic experimental data and MALDI-TOF-MS spectra ; Dataset
Format application/x-tar
Discipline Chemistry; Engineering Sciences; Materials Science; Materials Science and Engineering; Natural Sciences
Temporal Coverage 2021-2023