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Programme Access Rosseinsky
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Phase transitions in Sr-doped multiferroic bismuth ferrite
Bismuth ferrite, BiFeO3, is a much-studied ceramic showing both dielectric and magnetic ordering at relatively high temperatures. In order to improve its properties there has... -
Understanding the decomposition of ammonia by lithium-calcium imide
Among light metal amide-imide catalysts for ammonia decomposition, lithium-calcium imide is the most promising candidate for practical application. Ex situ diffraction data... -
Structure and phase transitions of Sr3Ru2O7
Sr3Ru2O7 is a layered Ruddlesden-Popper perovskite which displays intriguing behaviour at low temperatures and high magnetic field. It can be tuned close to a quantum critical... -
The structure of clay swelling inhibitors TMA and TEA under oil-field conditions
Shale swelling is particularly problematic in the oil and gas exploration sector, as environmentally friendly water based muds are invariably used during drilling operations to... -
The crystal structure and thermal expansion of orthorhombic NiSi
NiSi is a technologically important material that is also of interest to Earth Scientists because of the possible role of Ni and Si in the Earth¿s core. It crystallises in the... -
Structural phase transitions in Li doped AgNbO3.
The aims of the present proposal are twofold. Firstly to use very high resolution neutron diffraction data to establish accurate and precise structures of the novel... -
A variable temperature study of polymorphism in Li2MSiO4 electrode materials
There is great interest in scaling up Li-ion batteries for use in electric vehicles, requiring cheap and safe cathodes. Recently, silicate-based cathodes have been described,... -
Possible amorphous:amorphous phase separation in bioactive glass containing s...
There is an interest in understanding the nature of fluoro-alumino-silicate glasses based upon the apatite stoichiometric composition and of potential within ionomer cements for... -
INS STUDY OF BIOCHAR AS SOLID ACID CATALYSTS
Pyrolysis is considered as a sustainable way to generate energy from bio-oil, however, biochar – a solid residue by-product– is inevitably produced in the production line. We... -
Phase behaviour and dielectric phenomena in bismuth niobate energy storage ma...
Bismuth niobate (BiNbO4) is widely used in multilayer RF and microwave components such as capacitors and chip layer capacitors. This compound exhibits two main structural forms... -
A high-temperature neutron powder determination of the phase transition and c...
Cu2ZnSnS4 (CZTS) is a solar cell material of great interest. However the material when fabricated, although of high symmetry, contains substantial defect concentration and a... -
Misfit and Misfit Release in Co-Co3(Al,W) Superalloys
The effect of alloying additions (Ni, Fe, Cr, Ta, Mo, V, Ti, Si) on the misfit of developmental Co-Al-W alloys will be examined using Polaris. The Co3(Al,W) precipitate phase... -
Structure and cation ordering in A2Sn3Q7-type phases (A=In, Cr; Q= S, Se)
We wish to exploit the contrast afforded by neutrons to study the ordering of In and Sn cations in indium tin chalcogenides. Cation ordering has been inferred from spectroscopic...