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Study of structural and phase transitions of carbon dioxide confined in the n...
The properties of fluids confined in nanopores differ from the bulk mainly due to the solid-fluid interactions and the finite pore size. Such phenomena are of fundamental... -
Determination of the relative magnitudes of static and dynamic displacements ...
The width of a peak in a pair distribution function (PDF) provides a measure of the variation in the distance between a pair of atoms. This results from a combination of thermal... -
Pressure dependence of the mean kinetic energy of water protons
In a recent experiment [RB810044] we have measured the mean kinetic energy in supercooled bulk water at three pressures values in the range 200-4000 bar in order to shed light... -
Accounting for textural effects on total scattering data and the pair-distrib...
The total scattering technique has become an invaluable method for probing the local structure of materials in a host of interesting fields. However, the technique is reliant on... -
Opening up microemulsion phases in CO2
New types of water-in-CO2 microemulsions using mixed surfactant systems will be investigated by high-pressure SANS (HP-SANS). Exciting new results (see report on RB820030) have... -
Investigating the Structure of Porous Liquids
Porous liquids are a counter-intuitive new class of porous material consisting of a liquid with permanent, empty holes. They are unique in that they combine the fluidity of... -
Determination of the Pt-H bondlengths on a Pt/C fuel cell catalyst
We have recently demonstrated that it is possible to obtain structural information about adsorbed hydrogenous species from a variety of metal catalysts. We emphasise that this... -
Commissioning Proposal ¿ Gas Cell Development
An important element of the work associated with the current Framework Programme 7 Joint Research Activity (JRA) for muons is the development of gas sample pressure cells... -
Water soluble ruthenium compounds for homogeneous catalysis processes: the ro...
The combination of NMR, DFT based ab initio molecular dynamics (AIMD) and total neutron scattering aided by EPSR simulations provide a new method for understand the factors... -
Microscopic structure of nitric oxide (NO): A comparison between experiments ...
The Nobel Prize in Physiology and Medicine (1998) was awarded for the finding that nitric oxide (NO) is a ubiquitous signalling molecule in the cardiovascular system. Its... -
Kinetics of Molecular Intercalation into Graphite Oxide
The search for new porous materials is increasingly be driven by socio-economic pressure to diversify our energy supply and minimize environmental impact. Carbon-based... -
The Structure of Ca- and Yb-ammonia Solutions: Polarons, Bipolarons and Elect...
In this experiment we propose to perform diffraction on isotopically substituted samples of Ca/Yb:ND/H3 and Ca/Yb:15ND3 at two concentrations (8 and 2 MPM) using the new NIMROD... -
Nature of guest-host interactions in novel porous carbon materials
The goal of this proposal is to investigate the nature of the guest-host interactions in novel porous carbide-derived carbon (CDC) using TOSCA. The advantage of porous carbons... -
Carbon dioxide dynamics in a zeolitic imidazolate framework
Metal organic frameworks (MOFs) are three-dimensional networks consisting of metal cations/clusters linked through bridging organic ligands. Containing pores and cavities, such... -
Search for high pressure phase transitions in Bi0.8Ln0.2FeO3 (Ln = La and Tb)
The crystal and magnetic structures of two substituted variants of the multiferroic phase BiFeO3 will be studied as a function of pressure. Both Bi0.8La0.2FeO3 and... -
Direct validation of limiting total capacities of nanoporous hydrogen storage...
This set of experiments, which will utilize the new kbar pressure range BeCu gas sample cell designed for TOSCA, will experimentally validate the results of our mathematical... -
Hydrogen diffusion in Palladium-Silver membranes measured by QENS
Hydrogen selective membranes based on palladium are important for technological processes such as isotopic separation and gas purification.In general, a Pd membrane when... -
Kinetics of Hydrogen Abstraction in Alkanes by Mu Reactivity studied by RF Re...
Hydrogen abstraction reactions are key steps in free radical mechanisms that dominate the combustion and atmospheric chemistry of the alkane hydrocarbons and, as such, merit... -
Structural study of the higher oxidation states of the nickel positive electrode
Although the first patents involving the nickel positive electrode are more than 100 years old, our understanding of the phases involved in this system is still not complete. As... -
Structural Properties of Hydrogenated Ca-Intercalated Graphite Compounds
The recent discovery of superconductivity in Ca-intercalated graphite (C6Ca) has refocused considerable interest onto graphite intercalated compounds (GICs). We would like to...