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In-situ reaction of lithium amide or imide with manganese(IV) oxide
We request 3 days beam time on POLARIS for in-situ powder diffraction studies of the reactions of lithium amide or lithium imide with manganese(IV) oxide under flowing argon or... -
In-Situ Studies of Alternative Mobile-Ions for High-Temperature Thermal Batte...
Whilst rechargeable batteries continue to take over the consumer electronics market, they are unsuitable to replace specific battery technologies, such as the thermal battery,... -
In situ studies of mixed-phase oxygen transport membranes
The oxygen transport membrane is a system being developed by St Andrews in conjunction with industry, which at high temperatures will allow the selective migration of oxygen... -
Structural and Magnetic Characterisation of New Polar Oxides with Weak Ferrom...
The synthesis of a phase combining electrical polarisation P and spontaneous magnetisation M is hard because of the distinct electronic structure requirements for the main... -
Hydrogen from ammonia using lithium imide metal nitride composites
Light metal amides and imides are a new class of highly active ammonia decomposition catalysts. Indeed, composites of lithium imide and transition metal nitrides are likely to... -
In-situ neutron powder diffraction studies of non-stoichiometry in Na battery...
We request 3 days on POLARIS to study the detailed crystal structure of a sodium battery cathode material that is currently under consideration for use in commercial sodium... -
In-Situ Studies of Electrochemically Enhanced Performance in Perovskite Elect...
Recent studies in our laboratory have shown that a range of A-site deficient perovskite oxides, with carefully tuned chemical compositions, exhibit excellent properties when... -
In-situ studies of thermal electrochemical cells utilising transition metal s...
Thermal batteries are used in applications were high reliability is a key requirement. They can be stored for decades and activated in less than a second. Most contemporary... -
In-situ studies of amides with ammonia
The aim of this proposal is to determine that materials that are present in the ammoniation of amides. -
Hydrogen production from ammonia using lithium imide: an isotope study
We have recently discovered that light metal amides and imides are excellent cattalysts for the decomposition of ammonia. We request 3 days on POLARIS to perform in situ neutron... -
In situ studies on the decomposition of NaNH2 and possible formation of Na2NH.
Group 1 amides of general formula MNH2 are some of the most promising materials for hydrogen storage applications due to their relatively low temperatures of hydrogen evolution... -
In-situ Battery Discharge Studies of Thermal Batteries using Transition Metal...
Thermal batteries find use in applications such as emergency power systems and ejector seats in aircraft. They operate at elevated temperatures of around 400-500 °C, where the... -
Influence of cation ordering and Li content on solid solution behavior in LiN...
For energy storage applications, high energy density is an important material characteristic when searching for new types of suitable materials. LiNi0.5Mn1.5O4 (LNMO) is an...