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Molecular architecture of novel, trichain-containing vectors for gene delivery
We have recently developed novel ternary lipopolyplex vectors (i.e. gene delivery vectors containing cationic lipid, plasmid DNA and a cationic peptide) in which, for the first... -
Kinetics of Benzene Hydrogenation Revisited in the Presence of Excess Liquid
Heterogeneous catalysis, where the reagents are either contained in a liquid medium, or are liquids in their own right, plays a significant part of the chemical industry. These... -
Speciation and complex-ion formation in protic ionic liquids
The aim of this proposed study is to explore protic ionic liquids formed from by combining bis{(trifluoromethyl)sulfonyl}imidic acid (H[NTf2]) with imidazole and pyridine at... -
INS investigation of the decomposition intermediates for the destabilised mul...
Here we propose the investigation of intermediate compounds obtained during the decomposition of the multicomponent hydrogen storage system 2 LiBH4 : MgH2 using ex-situ... -
Neutron reflectivity of self-assembled Janus Nanoparticles
Here we propose to study the Janus character of self-assembled amphiphilic nanoparticles. For that amphiphilic core-shell nanoparticles will be synthesized with a surface... -
Understanding the molecular origin of co-non-solvency. Step 2.
A number of polymers that are commonly soluble in water and in alcohol, display a dramatic collapse when 10 molar % of alcohol is added to the polymer/water system. Various... -
Solubilisation of Drug Molecules in Nonionic Surfactant Micelles: Structural ...
This proposal aims to understand how the structure of non-ionic surfactant micelles affects the amount of fungicides solubilised. SANS is a technique unique for unravelling the... -
Impact of Stereochemistry and Diamine Structure on Absorption of Constructed ...
Chiral gemini surfactants containing stereogenic centers and two amphiphilic moieties, not only maintain the chiral properties, but also exhibit stronger aggregation properties,... -
Dynamic Long Range Antiferromagnetic Order in Frustrated Perovskites, Ba2-xSr...
We use chemistry to arrange unusual crystal structures that set up conflicting interactions between magnetic ions in the material. In these compounds i is not possible for a... -
Thermochromism in N-salicylideneanilines
N-salicylidineanilines are known to show thermochromic behaviour, which is currently postulated to arise from an intramolecular proton shift between the keto and enol form as... -
High Pressure Structure of Carbonic Acid
Recent published studies have identified a stable solid form of carbonic acid at high pressure. This proposal is for beamtime to collect the data to solve its crystal structure. -
Speciation and complex-ion formation in protic ionic liquids
A broad fundamental understanding of the design and properties of ionic liquids underpins their developing and future applications, which include accessing cellulosic polymers... -
Can photo-MuSR method measure carrier recombination lifetime in direct gap se...
In the past years we have developed a method measuring carrier recombination lifetime in semiconductors using the photo-MuSR setup in HIFI. These studies have focused on... -
Structures of ethanol ammonia cocrystals
Compounds of ethanol and ammonia have been known for over a century but no structural characterisation has ever been carried out. These materials allow us to examine a range of... -
Electric field dependence of the crossover from band to thermally assisted tr...
Organic semiconductors have been of major interest in recent years. Amplified by the transition from fundamental physics to new commercial products and technologies, this new... -
Use of nitric oxide radicals for the formation of a supramolecular hydrogel
The aim of this proposal is to study the structure of hydrogel systems formed from fluorenylmethyloxycarbonyl (FMOC) protected peptides, via the use of nitric oxide radicals.... -
Study of quadrupolar interactions in aromatic liquids: Benzene, hexafluoroben...
The non-covalent interactions between aromatic rings are of fundamental importance in large number biological and chemical processes. Examples include protein tertiary... -
In-situ Neutron Diffraction Studies of Lithium Battery Materials
This proposal seeks to test a new battery designed to allow in situ neutron diffraction measurements of lithium ion battery electrodes under charge and discharge. We have... -
A sustainability study of the galvanic deposition of silver from novel deep e...
The immersion deposition of silver onto copper and brass from deep eutectic solvents (DES) is a novel method for protecting the surface of printed circuit boards. Background... -
Polarised neutron reflectometry measurements in magnetic antidots arrays.
This study aims to observe the magnetic properties of a family of arrays of permalloy antidots. Antidots are grown, by means of magnetron sputtering, on top of an anodised...