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Quenched salt hydrates new ways of probing water clusters.
Very rapid quenching of liquids to form a glass, from which crystalline phases are subsequently obtained by devitrification, is a powerful technique for obtaining novel... -
Deuteration-induced phase transition in a multiferroic framework material
The hybrid organic-inorganic perovskites are of great interest as functional materials, because they combine the well-established perovskite topology with new physics and... -
Incommensurate-commensurate phase transitions in K2SeO4
Materials with incommensurate structures often show exotic properties (such as charge density waves). The development of reliable and efficient refinement techniques for such... -
Search for structural modulation lifting the orbital degeneracy in triangular...
This proposal is part of our research programme on spin and orbital order in frustrated systems. AgNiO2 has a layered crystal structure with Jahn-Teller active Ni3+ ions forming... -
In-situ reaction of lithium amide or imide with manganese(IV) oxide
We request 3 days beam time on POLARIS for in-situ powder diffraction studies of the reactions of lithium amide or lithium imide with manganese(IV) oxide under flowing argon or... -
Formation and ammonia decomposition behaviour of lithium nitride hydride
Ammonia is seen as a key part of the transition to a sustainable energy economy, but needs decomposition catalysts to release its stored hydrogen. Lithium nitride-hydride... -
Simltaneous dielectric spectroscopy and neutron diffraction
We have constructed a novel microwave frequency resonator that can sit within the GEM and POLARIS diffractometers and will allow us to simultaneously collect diffraction and... -
Sensing SO2 in Robust Porous MOF Materials via Simultaneous Microwave Dielect...
We seek to develop new MOFs for sensing and removal of toxic gases (e.g., SO2) and request 4 days on POLARIS to study the structural binding details and dielectric data... -
Low-energy magnetic excitations in the superconducting state of Sr2RuO4: open...
We propose to study the magnetic fluctuations of the unconventional superconductor Sr2RuO4 in the superconducting state extending our previous experiments on a cold triple-axis... -
Dental Cements and Inelastic Neutron Scattering: Meeting the Challenges of To...
In typical odontological studies water sorption in the restoration material is determined by weighing freshly mixed cement at regular intervals. In the case of resin-modified... -
In-Situ Studies of Alternative Mobile-Ions for High-Temperature Thermal Batte...
Whilst rechargeable batteries continue to take over the consumer electronics market, they are unsuitable to replace specific battery technologies, such as the thermal battery,... -
Cation substitution in synthetic meridianiite (MgSO4.11D2O): phase behaviour ...
MgSO4.11H2O (MS11) is the most highly hydrated phase in the binary MgSO4¿H2O system. Whilst lower hydrates in this system have end-member analogues containing alternative... -
Structural Distortions in the Spin Ladder Compounds Ba2CuTe1-xWxO6
Ba2CuTeO6 has garnered considerable interest as the combination of stacking sequence and Cu2+ displacements lead to a magnetic geometry that reproduce the effects of a spin... -
Modulation in Molecular Materials - Variable Temperature
Modulation occurs when there is ordering on two (or more) length scales. When the ratio of these is an integer, the modulation is said to be commensurate, i.e. one ordering is... -
Investigation of a Potential realization of the Nersesyan-Tsvelik Model in (N...
We propose to investigate the highly one-dimensional (1D) S=1/2 Heisenberg antiferromagnet (NO)[Cu(NO3)3] which is a potential realization of the Nersesyan-Tsvelik model. The... -
The chemical interaction and confinement effect of molecules in the sol-gel A...
Owing to the separation in the mesoscale and confinement effect of mesostructured pores to the molecule, mesoporous materials have been widely applied as matrices of host-guest... -
Investigating the formation of novel mixed amide-imide complexes and understa...
Inexpensive light-metal amides are among the most highly active and effective ammonia decomposition catalysts at modest temperatures and are likely to surpass the performance of... -
Polymorphism of phenytoin at low temperature
Phenytoin is a simple organic pharmaceutical material that exhibits a phase transition at low temperature to a new phase. The high temperature form exhibits some unusual... -
Uniaxial pressure effect in FeTe
Superconductivity in iron-based materials occurs in close proximity to a long-range ordered magnetic phase. In the iron pnictides, uniaxial pressure shifts the magnetic ordering... -
Looking at the motion associated with the cation and their freezing in TEA(TC...
The study of organic based materials is a popular topic and spans both chemistry and physics and presents some significant advantages. Of interest within this proposal is the...