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Understanding pressure-driven structural and magnetic properties in LaFeO3
This proposal is concerned with determining variations in the high pressure crystallographic and magnetic structure of LaFeO3. LaFeO3 is a characteristic example of... -
Understanding Deep Earth Mineralogy: A High P/T study of CaSiO3 Perovskite
CaSiO3 perovskite is the third most abundant mineral in the Earth's lower mantle; it also occurs as a major phase at lower pressures and temperatures in subduction zones, where,... -
Mixing CO2-philc surfactants and hydrotropes as a new approach to control vis...
One application where liquid CO2 has found success is enhanced oil recovery (CO2-EOR) of crude oil from porous rocks. However, a significant disadvantage of using CO2 in EOR is... -
Nonfluorous Cosurfactant/Hyperbranched Surfactant Mixtures for W/CO2 Microemu...
This proposal aims to explore cheap and environmental-benign cosurfactants (or cosolvents) for yielding CO2-philic hydrocarbon surfactant/water/CO2 microemulsions (W/CO2... -
Practical viscosifiers for supercritical CO2
This proposal explores headgroup-free, fluorocarbon-hydrocarbon hybrid compounds able toform viscous elongated aggregates in supercritical CO2 with the aim of improving... -
The formation of elongated aggregates in supercritical CO2 through the mixing...
This proposal involves manipulating the curvature of aggregated polar materials in supercritical CO2 (scCO2) by tuning the mixing ratio of fluorocarbon (FC) and hydrocarbon (HC)... -
The formation of elongated aggregates in supercritical CO2 through the mixing...
This proposal involves manipulating the curvature of aggregated polar materials in supercritical CO2 (scCO2) by tuning the mixing ratio of fluorocarbon (FC) and hydrocarbon (HC)... -
Novel gels with supercritical carbon dioxide
This proposal is to probe the gel structure with High Pressure SANS (HP-SANS) using an in-line pressure cell. The ability to control the properties of supercritical CO2,... -
Manipulation of the aggregate curvature in water/dense CO2 system
This proposal aims to investigate how the curvature of surfactant assemblies in water/dense CO2 systems can be tuned via the design and mixing of CO2-phillic surfactants. One... -
Generation of 3D-networks by mixing inexpensive HC-polymers, amphiphiles, and...
For the last two decades, many polymers have been tested to increase CO2 viscosity for enhanced oil recovery using CO2 (CO2-EOR). Unfortunately, conventional HC-polymers were... -
Probing the viability of water-in-CO2 microemulsions with Headgroup-free amph...
Recent SANS studies of an unusual headgroup-free surfactant (Nohead FC6-HC4) produced data that implied the formation of W/CO2 microemulsions (MEs) at a particular pressure (P)... -
High Pressure Driven Spin States in LaCoO3
This proposal is concerned with determining variations in the high pressure structure of LaCoO3 and observing changes within this as the material undergoes some well... -
Surfactant mixtures in CO2
Studies by the Bristol group, and elsewhere [1, 2], have shown that highly branched hydrocarbon chains is the key factor for generating effective non-fluorous CO2 philic... -
Exploring CO2-philic/ CO2-phobic amphiphiles, cross-linkers and HC-polymers f...
Over the last two decades, many polymers have been tested to increase CO2 viscosity for applications in enhanced oil recovery using CO2 (CO2-EOR). Unfortunately, conventional... -
CO2 foams stabilized by W/CO2 interfacially active hydrocarbon surfactants an...
CO2 foams can be formed in water/carbon dioxide (W/CO2) mixtures with the aid of W/CO2 interfacially active hydrocarbon surfactants and surface treated silica nanoparticles... -
Optimizing surfactants for CO2
This experiment addresses an important, and still unresolved, question in the field CO2-philic surfactants: what is the minimum fluorine content necessary to obtain a CO2-philic... -
W/CO2 nanodispersions as an energy-saving nanoreactor separable by pressure a...
Recent studies implied an unusual headgroup (HG)-free, fluorocarbon (FC) surfactant Nohead FC6-HC4 to form stable, W/CO2 nanodispersions (W/C NDs). With the unusual surfactant... -
SANS study of synthesis of interpenetrating polymer networks in supercritical...
We use SANS to study synthesis of interpenetrating polymer network in supercritical CO2 in situ at sans2D. The initial system contains an inorganic polymer network, hydrophilic... -
CO2-philic Low Surface Energy Surfactants for applications in Enhanced Oil Re...
In recent years, there has been an enormous interest in the study of surfactants for supercritical CO2 (scCO2). One important potential application of these materials is in...