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Apatite-type Oxides for Energy Applications: Symmetry Distortion Mode Analysi...
Apatites are a large group of chemically and structurally flexible functional materials with important applications as solid electrolytes. The majority of known apatite... -
Understanding Deep Earth Mineralogy: A High P/T study of CaSiO3 Perovskite
CaSiO3 perovskite is the third most abundant mineral in the Earth's lower mantle; it also occurs as a major phase at lower pressures and temperatures in subduction zones, where,... -
Does The Crystal Structure of Leucite Evolve with Temperature to the Proposed...
The concept of an aristotype, or equivalently, the basic structure, that represents the highest symmetry crystal structure that can be attained, either experimentally, or... -
Ferroelastic transitions in quantum critical tetragonal tungsten bronzes
Tetragonal tungsten bronzes have three types of channels for ions with the smallest unusually occupied with Li in potassium lithium tantalate (KLT). This creates complexity... -
Inelastic neutron scattering spectra of hydrogen absorbed in palladium-silver...
Pd-Ag alloys find technological applications in H uptake and purification. Among various peculiar properties, their electric resistivity variation as a function of the H loading... -
Spontaneous surface multilayer formation in oligoamine ¿ surfactant mixtures
This proposal is part of a major EPSRC (EP/GR065705)/Unilever funded programme to develop and control the spontaneous formation of surfactant multilayer structures at... -
Negative thermal expansion in V2OPO4
Much effort has been devoted to the research of new NTE materials and the understanding of the mechanism driving this phenomenon. As part of our ERC grant on orbital... -
Incommensurate-commensurate phase transitions in K2SeO4
Materials with incommensurate structures often show exotic properties (such as charge density waves). The development of reliable and efficient refinement techniques for such... -
Cation ordering in silicate spinel Ni2SiO4
Silicate spinels are important minerals in the transition zone region of the Earth and in order to understand seismic signals from these depths (550-660 km) we need to know the... -
Formation and ammonia decomposition behaviour of lithium nitride hydride
Ammonia is seen as a key part of the transition to a sustainable energy economy, but needs decomposition catalysts to release its stored hydrogen. Lithium nitride-hydride... -
Simltaneous dielectric spectroscopy and neutron diffraction
We have constructed a novel microwave frequency resonator that can sit within the GEM and POLARIS diffractometers and will allow us to simultaneously collect diffraction and... -
Neutron Total Scattering Investigation of Temperature Driven Transitions in L...
This proposal is concerned with determining the local structure of LaCoO3 and observing changes within this as the material undergoes some well characterised temperature driven... -
Sensing SO2 in Robust Porous MOF Materials via Simultaneous Microwave Dielect...
We seek to develop new MOFs for sensing and removal of toxic gases (e.g., SO2) and request 4 days on POLARIS to study the structural binding details and dielectric data... -
Investigation of ambient temperature polarity and magnetism in the ternary so...
Pb-based materials such as PbZrxTi1-xO3 (PZT) are widely used as transducers, actuators and sensors in a range of modern technologies due to their excellent piezoelectric and... -
Structure of Molecular Hydrogen in High Charge Pillared Clays
In this proposal we aim to study low temperature structure of hydrogen in the interlayer region of partially hydrated pillared clays. There are linked dual motivations for this... -
Structure Sequence in Ca(1-x)Nd2x/3TiO3 Ceramics
Microwave dielectric ceramics are used in communications devices. Such materials need high relative permittivity, high dielectric quality factor and be temperature stable.... -
Chasing the symmetry of the BiFeO3 γ-phase in the isostructural A- and B...
BiFeO3 is by far the most widely studied multiferroic material and yet many mysteries remain in the phase diagram. One mystery is the crystal structure of the high T gamma... -
Temperature induced structural phase transitions in BaPrO3 and acceptor doped...
The sequence of structural phase transitions that occur in distorted ABO3 perovskites as a function of temperature is of intrinsic interest for better understanding of the... -
In situ hydration study of the novel ionic conductor Ba7MoNb4O20
Oxide-ion and proton-conducting materials attract considerable interest thanks to their application as electrolytes in solid-oxide fuel cells (SOFCs). We have recently... -
Dynamics of Solid Ionic Conductors: Na2Si2O5 and Li2Si2O5
We would measure vibrational spectra for Li2Si2O5 and Na2Si2O5, as well as quasielastic neutron scattering (QENS) spectra for Na2SiO5. The measurement of phonon spectra in the...