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Understanding pressure-driven structural changes in FePO4-II
The room temperature high pressure behaviour of FePO4-I has been investigated and a phase transition at around 2.5 GPa to the orthorhombic phase (FePO4-II) accompanied by a... -
Quantum renormalisation of spin waves in a square lattice antiferromagnet
The two dimensional Heisenberg antiferromagnet on a square lattice is one of the most studied model in quantum magnetism . This is in part due to its intrinsic interest but also... -
Vacancy Distribution in Praseodymium Doped Ceria
Doped cerias are currently being used as oxide ion conducting electrolyte materials in solid oxide fuel cells (SOFCs). Depending on the nature and concentration of the dopant... -
Quantum dynamics in a J_eff=1/2 isotropic triangular-lattice antiferromagnet ...
This proposal is part of our research programme to explore the spin dynamics of strongly-frustrated quantum magnets. A canonical model is the spin-1/2 triangular antiferromagnet... -
Non-Fullerene Based Acceptors for Organic Solar Cells
Organic Solar Cells (OSCs) have attracted substantial commercial and scientific interest as they provide a pathway to realizing a renewable energy source that is portable... -
Measurement of spin-gravity coupling by quantum interference
It is possible that there is a coupling between the spin and gravitation, for instance by an adaptation of the Hamiltonian with an additional termH=k/c (gvec.Svec) where gvec is... -
A High-Pressure Low-Temperature Crystallographic Study of the Pm3m - I4/mcm F...
The perovskite-structured phases and their associated phase transitions remain an enduring topic of study within the solid state sciences due to their importance in both applied... -
In-situ reaction of lithium amide or imide with manganese(IV) oxide
We request 3 days beam time on POLARIS for in-situ powder diffraction studies of the reactions of lithium amide or lithium imide with manganese(IV) oxide under flowing argon or... -
Formation and ammonia decomposition behaviour of lithium nitride hydride
Ammonia is seen as a key part of the transition to a sustainable energy economy, but needs decomposition catalysts to release its stored hydrogen. Lithium nitride-hydride... -
Simltaneous dielectric spectroscopy and neutron diffraction
We have constructed a novel microwave frequency resonator that can sit within the GEM and POLARIS diffractometers and will allow us to simultaneously collect diffraction and... -
Sensing SO2 in Robust Porous MOF Materials via Simultaneous Microwave Dielect...
We seek to develop new MOFs for sensing and removal of toxic gases (e.g., SO2) and request 4 days on POLARIS to study the structural binding details and dielectric data... -
Micro-, Meso-, Macro- Structure and Dynamics of Biocompatible Dental Glass Io...
Glass Ionomer Cements (GICs) have found numerous applications as bone fillers, replacements and adhesives, particularly in dentistry due to their tooth like appearance and... -
In-situ lattice parameter and misfit analysis of a forged nickel-based supera...
Nickel-based superalloys have excellent high-temperature properties due to the dispersion of stronger precipitates in matrix. The properties are significantly affected by the... -
Configurational and displacive disorder in the cubic NTE material Cd(CN)2
Cubic cadmium(II) cyanide shows the most pronounced isotropic NTE effect known, with behaviour more than twice as extreme as that of better known materials such as ZrW2O8. This... -
Dental Cements and Inelastic Neutron Scattering: Meeting the Challenges of To...
In typical odontological studies water sorption in the restoration material is determined by weighing freshly mixed cement at regular intervals. In the case of resin-modified... -
In-Situ Studies of Alternative Mobile-Ions for High-Temperature Thermal Batte...
Whilst rechargeable batteries continue to take over the consumer electronics market, they are unsuitable to replace specific battery technologies, such as the thermal battery,... -
Characterising the amorphicity and porosity of ice aggregates in planet-formi...
With the discovery of almost 3000 exo-planets it is clear that planet formation is a by-product of star formation, yet in the micron ? cm size range, where relative velocities... -
The structure of methane water fluid mixtures at high pressure
We have recently discovered that above 2 GPa in the liquid/fluid forms water and methanebecome miscible in proportions up to 33 mole% of methane. This proposal is for time to... -
Structure of Cellulose Nanofibril Gels with Alcohols
Our group has been working partially oxidized cellulose nanofibrils which form gels in aqueous formulations. Recently we have observed that these fibrils also gel when dialysed... -
Temperature induced structural phase transitions in BaPrO3 and acceptor doped...
The sequence of structural phase transitions that occur in distorted ABO3 perovskites as a function of temperature is of intrinsic interest for better understanding of the...