-
Strain/order parameter coupling and anomalous elastic properties of Sr(Ti,Zr)...
HRPD data will be collected in situ at low and high temperatures from perovskites belonging to the Sr(ZrxTi1-x)O3 solid solution which have recently been characterised for their... -
Microstructural orientation mapping with a neutron beam
We propose to develop the means to measure the orientations, phases and strains of individual crystal grains within a polycrystal using neutrons. Such measurements have... -
Mechanism of hydride-ion mobility in a novel oxide-hydride
This proposal requests 7 days of beamtime on the quasielastic neutron scattering spectrometer OSIRIS to investigate the mechanism of hydride ion mobility in the recently... -
The role of Disorder in Phase Transitions in some manganese Perovskites
The aim of this work is to understand the origin of the difference in the behaviour between the two doped manganites Sr0.65Pr0.35MnO3 and Sr0.70Ce0.30MnO3. The hypothesis we... -
Ammonia synthesis using lithium hydride-metal nitride composites: an in situ ...
The development of more active catalysts for the production of ammonia will have a worldwide impact on the energy cost of producing fertiliser. Composites of lithium hydride and... -
The possibility of strongly ferromagnetic austenite in a stainless steel
It is generally accepted that austenitic steels (fcc) show no ferromagnetic signature. However, thermomagnetic measurements suggest an unexpected ferromagnetic transition (Tc =... -
Investigation of the low temperature phases of SrSnO3
The present proposal is to examine the low temperature structural properties of SrSnO3 using the HRPD. This work aims to examine the structural basis for the unusual low... -
Spatial, Chemical, and Temporal Resolution of Platinum-Catalysed Benzene Conv...
This proposal aims to study the potential for neutron diffraction to offer spatially-, chemically-, and temporally-resolved information on a dynamic system, in this case the... -
Does elastic twinning play a role in the thermal expansion behaviour of polyc...
We request two days of beam-time on POLARIS to obtain high resolution measurements of the thermal expansion of dolomite [CaMg(CO3)2]. The experiment forms part of a larger... -
The high temperature phases of multiferroic YMnO3
Hexagonal YMnO3 is a well-studied, but poorly understood, multiferroic material, which adopts the 'geometric' mechanism of ferroelectric distortion, rather than the more normal... -
Hydrogen production from ammonia using lithium imide: an isotope study
We have recently discovered that light metal amides and imides are excellent cattalysts for the decomposition of ammonia. We request 3 days on POLARIS to perform in situ neutron... -
A study on atomic clustering in Fe-Cr alloys by NIMROD diffractometer
Low temperature embrittlement of stainless steels are due to phase separation and it is known that the kinetics of phase separation depend on the initial structure. However, the... -
Understanding the decomposition of ammonia by lithium-calcium imide
Among light metal amide-imide catalysts for ammonia decomposition, lithium-calcium imide is the most promising candidate for practical application. Ex situ diffraction data... -
The crystal structure and thermal expansion of orthorhombic NiSi
NiSi is a technologically important material that is also of interest to Earth Scientists because of the possible role of Ni and Si in the Earth¿s core. It crystallises in the... -
Structural phase transitions in Li doped AgNbO3.
The aims of the present proposal are twofold. Firstly to use very high resolution neutron diffraction data to establish accurate and precise structures of the novel... -
In-situ investigation of nitrogenation process of (Nd,Zr)Fe10Si2 alloys
Tetragonal R(Fe,M)12 compounds (R=rare earth, M transition metal or Si), with the ThMn12 structure, are good candidates as permanent magnet materials with reduced R content.... -
A variable temperature study of polymorphism in Li2MSiO4 electrode materials
There is great interest in scaling up Li-ion batteries for use in electric vehicles, requiring cheap and safe cathodes. Recently, silicate-based cathodes have been described,... -
Investigation of the impact of mechanical twinning on the thermal expansion b...
We request three days of beam-time on POLARIS to investigate the influence of thermally-induced twinning on the thermal expansion behaviour of polycrystalline calcite....