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Programme Access Rosseinsky
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Phase transitions in Sr-doped multiferroic bismuth ferrite
Bismuth ferrite, BiFeO3, is a much-studied ceramic showing both dielectric and magnetic ordering at relatively high temperatures. In order to improve its properties there has... -
Nature of the ground state of Dy2Ti2O7 spin ice
Spin ice (SI) is a state of matter characterized by a residual (Pauling) entropy and unusual correlations. The huge interest in SI materials from the magnetism community stems... -
Understanding the decomposition of ammonia by lithium-calcium imide
Among light metal amide-imide catalysts for ammonia decomposition, lithium-calcium imide is the most promising candidate for practical application. Ex situ diffraction data... -
Investigating the speciation of hydrocarbonaceous deposits formed during oxid...
Propene plays an important role in various petro-chemical applications, such as the production of polypropylene and acrylic acid, but is dependent on the fluctuating prices of... -
The crystal structure and thermal expansion of orthorhombic NiSi
NiSi is a technologically important material that is also of interest to Earth Scientists because of the possible role of Ni and Si in the Earth¿s core. It crystallises in the... -
Structural phase transitions in Li doped AgNbO3.
The aims of the present proposal are twofold. Firstly to use very high resolution neutron diffraction data to establish accurate and precise structures of the novel... -
Reversibility of Transition Metal Migration upon cycling of Li-rich Cathode M...
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Oxygen deficient Na-ion cathode material (24)
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Structure of LixMn1-xN (x=0.83)
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A variable temperature study of polymorphism in Li2MSiO4 electrode materials
There is great interest in scaling up Li-ion batteries for use in electric vehicles, requiring cheap and safe cathodes. Recently, silicate-based cathodes have been described,... -
Pyrochlore to Defect- Fluorite Transition Studies in Holmium-Titanate based C...
Pyrochlore to Defect- Fluorite Transition Studies in Holmium-Titanate based Composition using Neutron Powder Diffraction Technique-5 -
Neutron Scattering and Structural Measurements of CO2 and CD4 Adsorption in M...
Shale is an increasingly viable source of economic quantities of natural gas worldwide. Most of the gas is contained within the fine pores, thus characterizing accessibility and... -
Possible amorphous:amorphous phase separation in bioactive glass containing s...
There is an interest in understanding the nature of fluoro-alumino-silicate glasses based upon the apatite stoichiometric composition and of potential within ionomer cements for... -
Phase behaviour and dielectric phenomena in bismuth niobate energy storage ma...
Bismuth niobate (BiNbO4) is widely used in multilayer RF and microwave components such as capacitors and chip layer capacitors. This compound exhibits two main structural forms... -
A high-temperature neutron powder determination of the phase transition and c...
Cu2ZnSnS4 (CZTS) is a solar cell material of great interest. However the material when fabricated, although of high symmetry, contains substantial defect concentration and a... -
Structure and cation ordering in A2Sn3Q7-type phases (A=In, Cr; Q= S, Se)
We wish to exploit the contrast afforded by neutrons to study the ordering of In and Sn cations in indium tin chalcogenides. Cation ordering has been inferred from spectroscopic...