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Quantum Methyl Rotors for Gas Sensing in Zeolitic Imidazolate Framework-8
We aim to utilise Low-Energy Neutron Scattering (LENS) at OSIRIS to investigate the effects of gas adsorption on the quantum rotation of the methyl groups present in a Metal... -
In-situ studies of thermal electrochemical cells utilising transition metal s...
Thermal batteries are used in applications were high reliability is a key requirement. They can be stored for decades and activated in less than a second. Most contemporary... -
Pressure Effects on Proton Migration 3,5-pyridinedicarboxylic Acid
Hydrogen bonds are ubiquitous in materials across the chemical spectrum, from inorganic to biological. They influence the structure, the functionality, and therefore the... -
Gas Loading Effects on the Quantum Methyl Tunnelling Phenomenon in Zeolitic I...
This proposal is a continuation access to a recent experiment conducted at OSIRIS (RB1510529) to study the quantum tunneling characteristics of ZIF-8, which is a cubic... -
Ammonia synthesis using lithium hydride-metal nitride composites: an in situ ...
The development of more active catalysts for the production of ammonia will have a worldwide impact on the energy cost of producing fertiliser. Composites of lithium hydride and... -
The role of step-size on the pressure phase diagram of BiFeO3
bismuth ferrite (BFO) remains the most studied multiferroic as a result of room temperature electric and magnetic ordering. However, real world applications are limited due to... -
Ordering in the La/W substituted bismuth oxide fluorite, Bi7W0.25La0.75O12.375
Materials that show fast oxide ion conduction have potential applications as electrolytes in devices such as solid oxide fuel cells (SOFCs), gas sensors and gas separation... -
Structural Studies of Li(ND3)n11BD4
On exposure to ammonia, Li(11)BD4 forms the ammoniate Li(11)BD4(ND3)n. Our recent experiment (RB820252) has shown that there are four distinct crystalline phases in the... -
Local structure studies in the pressure-induced order-disorder phase transiti...
BaTiO3 is often thought of as the classic example of a ferroelectric material, with a well-defined, widely-taught phase diagram. However, the nature of the ferroelectric phase... -
Quantum Methyl Rotors for Gas Sensing in Zeolitic Imidazolate Framework-8
We aim to utilise Low-Energy Neutron Scattering (LENS) at OSIRIS to investigate the effects of gas adsorption on the quantum rotation of the methyl groups present in a Metal... -
In-situ Hydrogenation of Calcium Nitride
Nitrides of alkali and alkaline earth metals are an interesting set of materials specifically for their potential in reversible hydrogen storage. However, many fundamental... -
Texture memory and variant selection for steel and titanium and zirconium alloys
The proposed experiment will focus on determining the level of texture memory and variant selection on both heating and cooling for steel and titanium and zirconium alloys with... -
Kinetics of Hydrogen Abstraction by Mu Reactivity with Propane studied by RF ...
Hydrogen abstraction reactions are key steps in free radical mechanisms that dominate the combustion and atmospheric chemistry of the alkane hydrocarbons and, as such, merit... -
In situ studies on hydride diffusion and exchange in alkaline earth hydrides ...
Thermogravimetric analysis on alkaline earth hydrides in St Andrews has revealed a remarkably fast exchange of deuterium and hydrogen by alkaline earth hydrides at relatively... -
In-situ investigation of nitrogenation process of (Nd,Zr)Fe10Si2 alloys
Tetragonal R(Fe,M)12 compounds (R=rare earth, M transition metal or Si), with the ThMn12 structure, are good candidates as permanent magnet materials with reduced R content.... -
Local ordering in the pressure-induced order-disorder transition in ammonium ...
Ammonium bromide undergoes a pressure-induced order-disorder transition, where the disordered (plastic) phase is thought to consist of a random distribution of ammonium cations... -
Heterogeneous hydrogenation in continuous flow followed by NMR and total neut...
It has been estimated that 80-90 % of chemical processes use catalysis in at least one step of the production process. Their use increases the energy efficiency of the process... -
Gas Mass Spectrometry of Gas Samples of the KTB Main Hole HB1g
In the complete KTB-VB and in in the KTB-HB down to a depth of 3003 m the gas phase was released and collected by twirl degassers attached in front of the mud shakers. This open... -
Gas mass spectrometry of gas samples from the KTB Main Hole HB1
The main objective of this drilling fluid analysis was the detection of inflows of formation fluids. Therefore different gases dissolved in the drilling mud were measured... -
Gas Mass Spectrometry of Gas Samples of the KTB Main Hole HB1d
In the complete KTB-VB and in in the KTB-HB down to a depth of 3003 m the gas phase was released and collected by twirl degassers attached in front of the mud shakers. This open...