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The effect of bilayer rigidity on the interactions with perfluoroalkyl compounds
Perfluoroalkyl substances (PFASs) are used extensively in industrial products although have been identified as emerging pollutants accumulating in wildlife and environment.... -
The Effect of Temperature on the Formation of Surfactant-Metal Ion Multilayer...
We have now established that multilayering at the air-water interface is a widespread phenomenon brought about by multivalent ions, whether polyelectrolyte, oligoelectrolyte or... -
The Impact of Multivalent Counterions on the Surface Adsorption of the Anioni...
Surface multilayer formation provides great potential for the tuning and optimising surface wetting properties and applications such as lubrication, drug delivery. Normally... -
Probing the structure of calcium silicates over a wide range of length scales.
Sol-gel derived calcium silicates are of great importance due to their ability to bond to bone and stimulate new bone growth. Diffraction has revealed the atomic-scale changes... -
Metal ion induced condensation of anionic fluorine-based conjugated polyelect...
In the proposed experiments we aim to characterise the structures of aggregate species formed when divalent metal ions, such as calcium(II), interact with the anionic conjugated... -
Novel Alginate Adsorption onto High Surface Energy Crystal Faces of Calcite
In this novel proposal we will investigate adsorption onto the non-equilibrium face of calcite the first time this has been attempted. This will compliment and extend our... -
Investigation of zwitterionic surfactant templated bio-polymer films as senso...
We have found it possible to deposit mesostructured surfactant templated polymer thin films on solid substrates. To date the majority of work has used hexadecyltrimethylammonium... -
Multilayering of Isostearic Methyl Ester Sulphonate at the Air-Aqueous Interf...
Surfactants usually form a single layer of molecules at the surface of water. We have shown that under certain conditions more than one layer may form. in which case the system... -
Micelle formation from model surfactant binary and ternary compositions in th...
The effects of electrolytes on SLES3, C12E8 and LAS4 has been extensively studied, especially the effect on the critical micelle concentration of each surfactant. We wish to... -
Amino-Acid Based Surfactant Monolayers on a Range of Subphases
Amino acid based surfactants have been known for many years but so far few detailed studies have been carried out on their properties. We are using amino acids extracted from... -
Kinetics of amphotericin B interaction with model human and fungal cell membr...
The increasing incidence of pathogenic fungi resistant to treatment with amphotericin B (AmB) has created a demand for novel anti-fungal agents. The successful development of... -
Adsorption of Sodium Polyacrylate onto a-Alumina
In this proposal we investigate the adsorption of the key dispersant additive, sodium polyacrylate, used in colloidal systems using neutron reflection on aluminium oxide, with... -
Thin Water Layers
The aim of this proposal is to determine the thickness of a water layer surrounding colloidal particles dispersed in oil with changes in ionic strength. Recent work by our group... -
New Approaches to Producing Floating Supported Bilayers
The complex sample environment needed for floating supported bilayers has often led to a need to constantly redevelop the system to improve reproducibility. Here we plan to... -
Multilayering of Methyl Ester Sulphonates at the Air-Aqueous Interface: Effec...
Surfactants usually form a single layer of molecules at the surface of water. We have shown that under certain conditions more than one layer may form. When this happens the... -
Complex evolution of solution microstructure in LAS / nonionic surfactant mix...
This proposal is part of a broad programme of collaborative research between RAL / Oxford and Unilever, using predominantly scattering techniques to investigate the nature of... -
Kinetics of surfactant multilayer formation / dissolution at interfaces
The spontaneous formation of multilayer structures at surfaces and interfaces from self-assembly in mixed surfactant and in polymer / surfactant mixtures are being increasingly... -
Neutron Reflection from a Biomineralisation Glycosaminoglycan on Calcite
Here we aim to structurally characterise the formation of adsorbed monolayers of heparin on calcite to address how these species influence biomineralisation and the inhibition... -
Multilayering of Isostearic Methyl Ester Sulphonate at the Air-Aqueous Interf...
Surfactants usually form a single layer of molecules at the surface of water. We have shown that under certain conditions more than one layer may form. in which case the system... -
Cellulose-based polyelectrolytes for microencapsulation: conformational trans...
Addition of multivalent salts to water soluble polyelectrolytes, such as sodium carboxymethyl cellulose (NaCMC), induces conformational change to the polyelectrolyte structure,...