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Polaris Calibration - 2023 FY Cycles
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Wittig Revisited: Cleaning up 50 years of Waste in Metal-Free Catalysis
Recent thereotical determinations on the Wittig reaction point to low energy (terahertz) vibrations in the ~15-50 meV region being responsible for selectivity of this industrial... -
Characterization of heterogeneous solvent structure in a carbon capture fluid
We propose to use neutron scattering experiments to gain molecular level insight into an intriguing liquid structure observed in a water-free CO2-capture solvent. Switchable... -
Practical viscosifiers for supercritical CO2
This proposal explores headgroup-free, fluorocarbon-hydrocarbon hybrid compounds able toform viscous elongated aggregates in supercritical CO2 with the aim of improving... -
The quest for attractive divalent sulfur - oxygen interactions
Weak nonbonded interactions between a divalent sulfur and an oxygen atom have attracted growing interest because of their roles in determining the structure and the biological... -
The effect of interface roughness on proximity induced magnetisation and inte...
Interface effects, including proximity induced magnetisation (PIM), play an import role in many spintronic devices employing heavy metal/ferromagnetic structures. Interface... -
Topotactically reduced phases containing square planar Co(II) centres
The topotactic reduction of Sr3Co2O5Cl2 and Sr3Co2O5.80 yields the Co(II) phases Sr3Co2O4Cl2 and Sr3Co2O5 respectively. These phases contain corner linked arrays of... -
Variable temperature studies and local structure analyses of LiFe1-xMnxPO4 na...
In order to probe Li content, cation distribution and defects in a series of LiFe1-xMnxPO4 nanoparticles, we propose the use of neutron powder diffraction and pair distribution... -
Structure-property relationships in Mo-based oxides for SOFC applications
Molybdenum based-oxides have recently attracted interest for use as electrolyte and electrode materials in Solid Oxide Fuel Cells. This proposal requests 5 days of beamtime on...