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Neutron diffraction of amorphous calcium carbonate
Amorphous calcium carbonate (ACC) is regularly listed as one of the known calcium carbonate phases, first being identified in 1984. Although ACC is inherently unstable, it is a... -
Interaction of Chiral Amino Acids and Sugars with Hydrated Vermiculite Clay
This proposal aims to provide an atomistic understanding of the adsorption of chiral amino acids and sugars on mineral surfaces using isotopically labelled reagents. Our... -
Single-crystal analysis of disorder in deuterated and protonated mirabilite
Mirabilite (Na2SO4.10H2O) is relevant to many areas of geology, planetary science, and even the construction industry. It occurs naturally in evaporite deposits, and even as... -
Structural characterization of the interactions between Ionic liquids and MOFs
This proposal aims to extend our understanding of ionic liquid structure and determine the effect of confinement on short alkyl chain length ionic liquid within a well ordered... -
Muon Spin Relaxation studies of Ni(TCNQ)2
Molecular ferromagnets offer great potential as they are synthesized at low temperatures and offer the possibility functionalization. Ni(TCNQ)2 is such a molecular ferromagnet,... -
Structure Solution of the High-Pressure Polymorphs of Hydroxylamine
This proposal requests the allocation of six days beamtime on PEARL to collect neutron powder diffraction data suitable for the structure solution of phases II and III of... -
Local structure study of the order/disorder ferroelectric transition in [ND4]...
We will carry out a definitive local structure investigation of the ferroelectric transition in [ND4][Zn(DCOO)3]. This compound is seen as the canonical example of a... -
The solution structure of the OmpF¿Colicin N complex in lipid nanodiscs
We have previously solved the structure by SANS of the complex between the outer membrane protein F of E coi and the toxin colicin N which is a large antibiotic protein. This... -
Distribution of comonomer units in biodegradable semicrystalline copolymers
Aliphatic polyesters are the most attractive candidates for biodegradable polymers. To improve their physical properties while maintaining biodegradability, incorporating... -
Telechelic Polymer - Homopolymer Blends
We have recently embarked on a new 1 year project funded by Michelin to explore the self-associatation and mechanical properties of telechelic rubbery materials. Such materials... -
Lithium amide: calcium hydride (1:1) as the basis for a new hydrogen storage ...
A definitive structural model of LiCaN from powder neutron diffraction (PND) is an important first step towards a systematic study of the process and mechanism of hydrogenation... -
An investigation on the adsorption of reverse pluronic and additives on metal...
PPO-PEO-PPO copolymer-based lubricant with extreme pressure or friction modifier additives has been introduced as boundary lubricant in metal forming. The Pluronic reverse... -
Neutron reflectivity study on sefl-repairing polymer brushes by surface segre...
We have recently studied the surface segregations of amphiphilic block copolymers blended in a matrix of cross-linked poly(dimethyl siloxane). In this system, while the... -
Measuring phospholipid flip-flop rates across vesicle bilayers
Asymmetry across biological membranes is vital for a wide range of organelle and cellular functions. Significant differences in lipid composition have been found between the... -
Neutron diffraction of fully deuterated amorphous calcium phosphate (d-ACP)
Bone growth involves the formation of hydroxyapatite, HA, nanocrystals in the body. In vitro studies showed that HA does not precipitate directly, but that amorphous calcium... -
W I F David - Energy Project
W I F David - Energy Project -
Inelastic Neutron Scattering Experiments in the Sulfur-Ammonia Photothermoche...
The following proposal aims to ellucidate the role of ammonium ions in sulfite oxidation reaction. The key step in the sulfur-ammonia photothermochemical cycle, which is one of... -
Pressure Effects on Proton Migration 3,5-pyridinedicarboxylic Acid
Hydrogen bonds are ubiquitous in materials across the chemical spectrum, from inorganic to biological. They influence the structure, the functionality, and therefore the... -
Can surfactants be pushed out of polymer layers by applying compression?
For many applications such as paints, foods and drug formulations, aggregation of colloidal particles is prevented by combining polymer and surfactant adsorption. Key to this... -
In-situ study of structure-property relationships on proton conducting perovs...
Significant research has been given towards synthesis and characterisation of electrolyte materials with high proton conductivity for intermediate temperature range (200-600°C)...