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Modification of an adsorbed cationic layer by anionic surfactants below the CMC
In this proposal, we request beamtime to study the unexpected behaviour of a strongly bound bilayer of the cationic surfactant didodecyldimethylammonium bromide on the anionic... -
The role of water in homogeneous catalytic processes mediated by water solubl...
A large number of chemicals are currently obtained by catalytic synthetic processes, but usually in most of these processes the catalyst remains in the reaction medium during... -
High pressure for liquids project on SANDALS
This beamtime request is part of a long term project based on the liquids diffractometer SANDALS and aimed at developing the use of Paris-Edinburgh press for liquids and in... -
Solution Study of the Interaction of Salt Species at Varying Concentrations
6 days on Nimrod are requested to collect neutron total scattering data of 1M, 2M and 3M solutions of a α,ω-dicarboxylic acid, glutaric acid, and 2-methylimidazole... -
The structure of water in halloysite nanotubes
Water is important in many scientific and technological areas, yet our understanding of this remarkable liquid remains very incomplete. In may cases, it is the properties of... -
Investigating the speciation of hydrocarbonaceous deposits formed during oxid...
Natural gas comprising mainly methane, ethane and propane is widely used as a raw material for different petrochemical applications. For example, polyethylene and poly-propylene... -
Hydration and sweetness of synthetic sweeteners
Recently, the degree of sweetness of natural sugars has been associated and correlated to their hydration shell (strength, orientation and length of their hydrogen bonds with... -
Encapsulation of Hydrophobic Species in Surfactant Micelles
Our recent work demonstrates that the details of water structure around micelles are now accessible using Empirical Potential Structure Refinement methods combined with neutron... -
The structure of solvents around 2d graphene oxide nanoparticles
Graphene oxide (GO) is an important starting material for developing chemically modified graphene for use in a variety of important technical applications that include... -
Low temperature studies of glycerol and aqueous glycerol
Glycerol, a sugar alcohol with three hydroxyl groups, is a rich and complex system for the study of hydrogen bonded fluids and has been the subject of long-standing scientific... -
Scrutinizing the role of the counterion in the axial coordination of the Pd(I...
The solution chemistry of Pt(II) and Pd(II) cations has attracted experimental and theoretical attention because of their relevance in catalytic processes and the... -
The hydration of sucralose
We found in our previous experiments (RB numbers 810202 Determination of sugar hydration shell and water structure in different water-sugar mixtures''(glucose, fructose,... -
Liquid-liquid immiscibility and glass transitions in aqueous solutions
The microscopic structure of a dilute solution of LiCl in water is determined at different thermodynamic states in both the liquid and glassy phases. This solution exhibits... -
Structure of water subjected to a static electric field
The behavior of liquid water under an electric field is a crucial phenomenon in science and engineering. However, its detailed description at a microscopic level is still far... -
Glycine association under extreme environmental conditions
There is a huge interest in the properties of water under extreme conditions of temperature, pressure and environment. This interest ranges from the water vapour jets that... -
Structural comparison of peptidomimetic building blocks
Peptidomimetics are synthetic mimics of peptides, the natural building blocks of proteins, and their development is a growing field of science. An underlying theme in recent... -
The Ability of Trimethylamine N-Oxide to Resist Pressure Induced Structural P...
Trimethylamine N-Oxide (TMAO) is thought to have the extraordinary ability of allowing organisms to adapt to extreme environments of high pressure, the most famous example being... -
Structural characterization of water confined in MCM-41
By combining NDIS experiment and EPSR simulation we have been able to show with a previous experiment (RB 720500) two main phenomena for water confined in the MCM silica matrix.... -
The origin of the dissolution of cellulose in NaOH/urea aqueous solution at -...
Cellulose is produced over tens of billions of tons every year in the world. It is the one of the most abundant natural polymer resources. Compared with petroleum-based... -
Linking the solid state and solution thorium aqua structures: solution struct...
A understanding of the aqueous chemistry of the actinide ions is not as well developed as for transition metals or the lanthanides. Fundamentally important information such as...