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Distribution of End-Functionalized Polymers in Semi-Crystalline Blends
Although the surface properties and self-organisation of end-functional polymers in amorphous blends are well understood, the influence of crystallinity has received little... -
Molecular Weight and Incipient Crystallinity Effects on Polymer Surface Segre...
We have established multi-end functional polymers as potent additives for spontaneous surface modification of blends. Since semi-crystalline polymers such as PE, PP, PET could... -
pH Responsive Polymer Blend Surfaces
Polymers, end-functionalised with carboxylic acid (COOH) groups do not normally segregate to film surfaces due to the high surface energy of these functionalities. However, we... -
Study of carbon supports for catalysts used in the direct synthesis of hydrog...
We have recently shown that acid washing of a carbon support prior to metal (Au, Pd) deposition enhances the activity of the resulting catalysts for the direct synthesis of... -
INS studies of the oxidation of benzyl alcohol using supported AuPd nanoparti...
This proposal is a continuation of RB1000003 and RB1110113. The aim of the present experiment is to gain further insight into the mechanism of benzyl alcohol oxidation using... -
Investigation of the core-shell interaction in stabilised PdAu nanoparticle c...
Bimetallic nanoparticles are attractive materials due to their novel electronic, magnetic optical and catalytic properties which are distinctly different from those of their... -
Understanding the mechanism of benzyl alcohol oxidation using supported Au-Pd...
This proposal is a continuation of RB1000003. The aim of the present experiment is to gain further insight into the mechanism of benzyl alcohol oxidation using supported Au-Pd... -
Structural Investigation of high active Lewis acid catalysts for selective hy...
The selective oxidation of saturated C-H bonds is a crucial step in many industrial processes. Recent we have discovered an alternative green one-step route for the selective... -
Understanding Melt Phase Aggregation in Semicrystalline Polymer Blends
We have recently prepared and studied the surface properties of some well-defined multi-end functional polyethylenes. Whilst most of our surface studies indicate that these... -
Matrix Effects on Polymer Surface Segregation
We have used neutron reflectivity and complementary techniques of ion beam analysis and contact angle to understand the adsorption behaviour of multi-fluoro end functional... -
Aggregation of Polar Multi-end Functional Polymers
Polar functional groups on polymer chains are of particular interest for applications in adhesion, printing, biocompatibility and mineralisation. We have created a series of... -
Understanding the mechanism of benzyl alcohol oxidation using supported Au-Pd...
Gold, in its nano-scale, has been found to be very effective catalyst for oxidation reactions. More recently, it was shown that supported Au-Pd catalysts can be used for... -
Investigation of the nature of organic surface species formed on Au-based sup...
The objective of this proposal is to spectroscopically identify the nature of surface species formed during the addition of tert butyl hydroperoxide onto the surface of the...