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Correlation between Internal Dynamics and Microstructure in Ionic Micelles
Despite the extensive characterization of the structure and macroscopic behavior of micelles, the fast local dynamics of surfactants in micelles and their correlation with... -
Nanostructure in Ionic Liquid mixtures
In recent SANDALS experiments, we showed that simple ionic liquids (ILs) ethylammonium nitrate (EAN) and ethanolammonium nitrate (EtAN) are structurally hetereogeneous, with... -
Ionic Liquid ¿ Water Interactions
This project aims to examine the structure of microemulsions formed by water and 1-methyl-3-ethylimidazolium-based ionic liquids with the acetate or octanoate anion. These... -
Ionic disorder and phase transition studies of Lightweight Hydrides LiBH4 and...
We ask for 3 days on EMU to study the Muon spectroscopy of both LiBH4 and Ca(BH4)2 as a function of temperature from 90K-650K. These materials have been extensively... -
Structural characterization of the interactions between Ionic liquids and MOFs
This proposal aims to extend our understanding of ionic liquid structure and determine the effect of confinement on short alkyl chain length ionic liquid within a well ordered... -
Protic Ionic Liquid ¿ Benzene Interactions
Ionic liquids (ILs) have been extensively studied for liquid¿liquid extractions and have recently been examined for the purification and separation of crude oil components. Of... -
Understanding Micelle Formation in Binary Ionic Liquid Mixtures
Neutron diffraction will be used to investigate and compare the structure of binary mixtures of ionic liquids above and below the critical micelle concentration. Mixtures of... -
Understanding Amphiphilic Self-Assembly in and by Protic Ionic Liquids
The goal of this project is to understand the intermolecular forces that promote amphiphile self assembly in ethylammonium nitrate (EAN), a room temperature ionic liquid (IL).... -
Ionic Liquid Aggregation in Polymers
Ionic liquid/Polymer mixtures, where the ionic liquid is the minority component are of particular interest for their potential as high temperature plasticisers and conducting... -
An ALC study of the organic ferroelectrics TTF-CA and TTF-BA
The study of organic ferroelectrics based on mixed-stack charge-transfer salts is currently a rapidly developing research field. These materials attract interest as highly... -
Atomic and Ionic Mobility in Glass Ionomer Cements (GICs)
A proposal is made to measure atom/ion mobility/diffusion in GIC samples. Vesuvio is ideal to explore diffusion of ions bound by ~0.5-5eV bond energies and covalently bound... -
Effect of Concentration Charge and Ionic Strength on Adsorption of Small Part...
Despite the wide practical interest in particulate colloids there have been few studies that exploit the advantages of reflection and neutron scattering to study adsorption of... -
Nuclear Structures of Lithium Substituted Layered Transition Metal Oxide Cath...
Novel cathode materials for rechargeable batteries have been under intense investigation since high cost and toxicity of current Li-ion batteries. We propose to study the... -
Translational and Rotational Dynamics of Imidazolium based Ionic Liquids
High-resolution quasi-elastic neutron scattering (QENS) will be used to study the dynamics in pure RTILs [Bmim][PF6] and [Bmim][TfO] and their solutions in acetonitrile-d3 (AN).... -
Ionic disorder studies of lightweight hydrides by VESUVIO
We ask for 8 days on VESUVIO to study the momentum distribution of LiBH4, Li2NH and Li1+xNH2-x as a function of temperature from 10K-653K (depending on sample). Li2NH and... -
Ionic radius perturbation on water hydrogen bond network
The salts composed by elements of the first period with halogen elements are a family of compounds with different anionic and cationic combination. In this proposal we aim at... -
Salts Dissolved in Salts: Ionic Liquid + inorganic salt mixtures
Ionic liquids (ILs) are low melting point organic salts that until recently were thought to have homogeneous microstructure. In recent SANDALS research,1 we showed pure ILs are... -
Effect of Variation in the Anion on the Bulk Nanostructure of Protic Ionic Li...
In a recently published note we presented the first experimental evidence (obtained using the LoQ instrument at ISIS) for nanoscale segregation of short (< C4) alkyl chain...