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Spin Rotation Experiments at a Pulsed Muon Source using Broadband RF Pulses
In this proposal we wish to explore how the RF-uSR technique might be developed for measurements akin to FT-NMR. Our work will focus on the broadband excitation of paramagnetic... -
Kinetics of Hydrogen Abstraction in Alkanes by Mu Reactivity studied by RF Re...
Hydrogen abstraction reactions are key steps in free radical mechanisms that dominate the combustion and atmospheric chemistry of the alkane hydrocarbons and, as such, merit... -
A Study of AuMu^+ Final States by Dia RF Resonance
Small-sized metal nanoparticles (NPs) are of long standing interest to both magnetism and heterogeneous catalysis. Muon studies of Au NPs encapsulated in 'SBA-15' silica are... -
RF μSR in the gas phase: understanding a ¿null¿ result
We have made a significant effort to develop Radio Frequency μSR (RF μSR) as a technique for spectroscopy of organic radicals in the gas phase. Realising this method... -
Kinetics of Hydrogen Abstraction in Butane by Mu Reactivity
Hydrogen abstraction reactions are key steps in free radical mechanisms that dominate the combustion and atmospheric chemistry of the alkane hydrocarbons and, as such, merit... -
A study of Line Broadening of the Muonium RF Signal in the Presence of O2 Spi...
Considerable work has been carried out at ISIS with the aim of studying muoniated radicals in the gas phase by RF techniques. This has been motivated both by a desire to... -
Kinetics of Hydrogen Abstraction in Alkanes by Mu Reactivity studied by RF Re...
Hydrogen abstraction reactions are key steps in free radical mechanisms that dominate the combustion and atmospheric chemistry of the alkane hydrocarbons and, as such, merit... -
Multinuclear Radiofrequency Decoupling in Lithium Hydroxide
This proposal seeks to develop the technique of multinuclear RF decoupling and apply it to the study of lithium ion mobility in Lithium Hydroxide. Key to the understanding of... -
Towards a Method of Quantifying Electrophilicity and Nucleophilicity
Understanding of chemical reactivity is founded on the fundamental concepts of Electrophilicity and Neucleophilicity. All extant attempts to do this depend on the reaction of... -
Kinetics of Hydrogen Abstraction in Alkanes by Mu Reactivity studied by RF Re...
Hydrogen abstraction reactions are key steps in free radical mechanisms that dominate the combustion and atmospheric chemistry of the alkane hydrocarbons and, as such, merit... -
RF MuSR in the gas phase: the Search for a Radical State
The main spectroscopic technique for studying radicals in solids and liquids, ESR, cannot usually be used to study radicals of more than 3-5 atoms in the gas phase due to strong... -
Kinetics of Hydrogen Abstraction in Alkanes by Mu Reactivity studied by RF Re...
Hydrogen abstraction reactions are key steps in free radical mechanisms that dominate the combustion and atmospheric chemistry of the alkane hydrocarbons and, as such, merit... -
RF MuSR in the gas phase: The Search for a Radical State
The main spectroscopic technique for studying radicals in solids and liquids, ESR, cannot usually be used to study radicals of more than 3-5 atoms in the gas phase due to strong... -
A Study of AuMu^+ Final States by Dia RF Resonance
Small-sized metal nanoparticles (NPs) are of long standing interest to both magnetism and heterogeneous catalysis. Recent muSR studies of Au NPs encapsulated in mesoporous... -
Solution Aggregation of Short Peptide Amphiphiles
Short peptide sequences consisting of hydrophobic and hydrophilic amino acid units are capable of self-assembly, leading interfacial adsorption and solution nano-aggregation.... -
Diffusive behavior in garnet-type Li ion conductor under electric field
This proposal describes a muSR experiment on a garnet-type Li ionic conductor, Li6.75La3Zr1.75Nb0.25O12 under electric field (E) in order to study a diffusive behavior under a... -
Kinetics of Muoniated Radicals Studied With Radio Frequency Muon Spin Resonance
Radio-frequency muon spin resonance is a powerful technique for studying free radicals and their reaction kinetics, but it has not yet been used to study complex reactions in... -
Structures of New Niobates Prepared by Hydrothermal Synthesis
We have prepared some new highly crystalline mixed-metals oxides using mild hydrothermal reaction conditions. Some of these are doped niobates, related to the important...