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Structural and magnetic studies of the alkali sesquioxides Rb4O6 and Cs4O6
The mixed-valence sesquioxides A4O6 (A = alkali metal) are particularly intriguing magneticmaterials comprising of non-magnetic (O2)2- and magnetic (O2)- anions. Recent... -
Valence bond solid in the charge ordered state of Rb4O6
Open p-shell anionic mixed-valence compounds have been recently proposed as intriguing model systems for disentangling the complex interplay of charge, lattice, orbital, and... -
Field-induced low-temperature magnetic phase in alkali-metal sesquioxides
Open p-shell anionic compounds are model systems where the interplay between charge, lattice, orbital, and spin degrees of freedom leads to complex magnetic behavior. In the...