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Novel proton environments in geologically important hydrous silicates
Hydrous chain silicates (amphiboles) are central to understanding many geological processes in the Earth¿s Crust, Upper Mantle and Transition Zone, where they influence melting,... -
Determining the Crystal and Magnetic Structures of [Li(oxalate)]2[Co5(OH)8]
Dense corrdination frameworks that contain inorganic centres connected into extended lattices by polyatomic anions often adopt highly anisotropic structures. Thus they often... -
Understanding the formation of diamonds: Calibrating the coesite solid-inclus...
Diamonds provide our only direct samples of the very deep Earth and understanding their origin is consequently of great interest to Earth Scientists. The origin of diamonds can... -
Melting point dynamics of Confined fluids
This proposal aims to investigate the dynamics of the melting transition in H2O and CO2 when confined in a vycor (SiO2) matrix. The field of fluids in confined geometries is... -
The Dynamics of Molecular Hydrogen in Synthetic Clays
In this proposal we aim to study the low temperature uptake and dynamics of hydrogen in the interlayer region of partially hydrated pillared clays. There are linked dual... -
Isotopologue commisioning
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Structural and magnetic characterisation of polar magnetic perovskite-based m...
A new generation of low-power high-density information storage would be enabled by the development of ?multiferroic? materials which function at or above room temperature. Such... -
Magnetic order in the first hybrid layered fluoroperovskites
Layered perovskites are well known functional materials but, in the context of fluoride chemistry, have so far been restricted to purely inorganic examples: K2NiF4 is the... -
Define the crystal structures of lead-free ferroelectric, candidate multiferr...
We have a range of new structures in the lead-free ferroelectric, candidate multiferroic and SOFC cathode areas. The HRPD data will be used to define these new crystal... -
Hydrogen Uptake by Pillared Graphite Oxides
High sorption capacities and enhanced interaction strengths are the two most fundamental prerequisites for the deployment of carbon-based materials as hydrogen-storage media. In... -
Kinetics of Molecular Intercalation into Graphite Oxide
The search for new porous materials is increasingly be driven by socio-economic pressure to diversify our energy supply and minimize environmental impact. Carbon-based... -
What is the Room Temperature Structure of NaTaO3?
The current proposal seeks to establish the origin of t non-perovskite-like peak splitting observed in HRPD data for NaTaO3. It is our hypothesis that this is a result of the... -
Interactions Between Ionic Liquids and Water
To date many papers have been published on the effects of impurities on the physical properties of ionic liquids (near room-temperature molten salts), however, only few studies... -
CaTiO3 cooling from 291 K 30-130 ms jaws 15*20
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Determination of the magnetic field-temperature phase diagram in metal-organi...
Metal-organic magnets are of interest primarily due to the synthetic versatility enabled by the vast array of organic complexes which can be used to coordinate magnetic ions and... -
Structures and magnetism of chemical and electrochemical deintercalates of la...
We propose to use POLARIS to perform two related experiments. Firstly we will investigate the structures and compositions of derivatives of some layered Mn/Cu oxysulfides which... -
Polycarbonate and tetramethyl bisphenol A polycarbonate
The miscibility of polycarbonates (PC) with polystyrene (PS) appears to be closely related to chain dynamics. Among all polycarbonates, tetramethyl bisphenol-A polycarbonate... -
The effect of redox on the substitution mechanism of Ti in meteoritic hibonite
We request 3 days of beam-time on HRPD to identify the substitution mechanism of Ti3+ and Ti4+ in synthetic hibonites [CaAl12O19]. The experiment forms part of a larger... -
Equation of state of ice VI
Ice VI is likely to be a major mantle mineral in the interiors of large icy moons in our solar system, and in large icy extrasolar planets. It is also a common accessory phase... -
Magnetically Driven Ferroelectric Order in the 2D Antiferromagnet b-NaMnO2.
Incommensurate magnetic phases generated by frustrated magnetic exchange interactions can stabilise novel induced magnetoelectrics. We have recently found that the...
