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Understanding the spin-Peierls Transition in KTCNQ and derivatives
Motivated by work showing that magnetic coupling between TCNQ anions in potassium TCNQ (KTCNQ) can be changed simply by changing the aromatic substituents, we seek to qunatify... -
Aggregation of chiral catalysts based on the Trost ligand
The project represents a new application of SANS to investigate chemically sophisticated chiral catalysts, addressing important questions in modern synthetic and catalytic... -
The electronic structure and magnetic properties of metal nanoparticles stabi...
In recent years, nanoparticles have been a major source of interest in a wide range of fields. Our long term objectives are tuning the free radical reactivity on the surface of... -
The structure of nanographenes in solution
In this proposal we will study the structure of metal-ammonia solutions containing single graphene sheets by exploiting H/D isotopic labelling in conjunction with NIMROD¿s... -
The effect of metal nanoparticles on the electronic structure of bound free r...
In recent years, the noble metals nanoparticles (MNPs) have been the subject of intense interest in areas of materials science, biotechnology, medicine and organic chemistry for... -
Controlling diblock co-polymer morphologies via selective solvent annealing
Diblock co-polymers consist of two polymer chains with different chemical properties tied together at a central linking block. The interactions between the two blocks result in... -
Generalising the link between catalytic activity and low-energy normal modes ...
Our recent theoretical and experimental characterisations of novel Pd N-heterocyclic carbene catalysts showed a clear relation between low-energy normal mode energies and... -
Helium quantum rattling in clathrate hydrate cages studied through neutron Co...
The proposing team is interested in exploring the low-temperature quantum "rattling" dynamics of helium atom(s) trapped in water-based cages (namely the so-called "clathrate... -
Are hydrotropes a unique class of solutes?
The aim is to improve understanding of solution properties and aggregation of hydrotropes and alkyl¿hydrotropes, and the relationship with common surfactants. Although they are... -
Spontaneous solvation of graphene from KC24(NH3) and KC8 graphite intercalati...
Liquid phase exfoliation of graphite is a scalable method for the production of graphene with an inbuilt medium for the manipulation of the graphene into applications. Much like... -
Conformational behaviour of amphiphilic polymethacrylate-poly(acrylic acid) c...
We intend to use small angle neutron scattering to investigate the conformational behaviour of a range of amphiphilic copolymers comprising a hydrophobic methacrylate segment... -
The structure of ammonia borane in water, DMSO and THF
There is an increasing urgency to find stable and lightweight hydrogen storage materials for clean transport applications. Promising options being investigated include Mg-based... -
Characterisation of on-top hydrogen on fuel cell catalysts.
A key step in a fuel cell is the dissociation of hydrogen gas to provide protons and electrons by a catalyst. For low temperature fuel cells carbon black supported... -
Using SERGIS, SESANS and NR to probe nanoscale cavities created within templa...
Nanoporous membranes fabricated by polymerization around soluble templates have found many applications in (bio)sensors, charge storage devices, filtration and catalysis.... -
The structure of nanographene and nanographite intercalates in solution
We aim use SANS to study in situ structure of solutions of uncharged and charged graphene formed by dissolving graphite and graphite intercalation compounds. We wish to compare... -
Silicon nanoparticles in thermoelectric material applications - Solution stat...
In order to meet the UK's commitment to reduce 80% of greenhouse gas emissions by 2050, it is necessary make major advances in efficient, clean and secure energy conversion and... -
Diffusion of molecular hydrogen into pre-formed THF clathrate hydrate
The proposing team has a well established experience in the use of neutron scattering on samples containing molecular hydrogen, and has recently studied some aspects of the... -
Effect of monodispersity on core crystallinity, core packing and nanoparticle...
The still unreached goal of nanomedicine is to deliver drugs which are only released in the diseased tissue in a controlled fashion. For this, tailorable, reproducible, and...
