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manipulating surface adsorption usinf ethoxylated polyelectrolytes
The strong interaction between polyelectrolytes and ionic surfactants can result in pronounced surface adsorption and the formation of surface multilayer structures. This... -
Surface structures of polycations in confined geometries
A second-generation surface force style apparatus has been developed to probe the inter-surface and near-surface structures under compressive forces. Systems of current academic... -
PNR measurements of the induced magnetisation in nanocarbon.
Nanocarbon materials such as C60 show fascinating transport properties when in contact with a ferromagnet. Previous results indicate that this could be due to a spin polarized... -
Ordering and interfaces in deuterated semiconducting liquid crystal/polymer s...
The main objective of this proposal is to study the structure of the interface between a semiconducting liquid crystal (LC) and a soft dielectric substrate for their potential... -
Surface Layer Structures of Short Peptide Amphiphiles
Short peptide sequences consisting of hydrophobic and hydrophilic amino acid units are capable of self-assembly, leading to interfacial adsorption and solution nano-aggregation.... -
The interaction of Plant Defensins with Model Lipid Membranes : Understanding...
Plants do not have the sophisticated immunoglobulin immune systems of vertibrates, instead they posses a series of stimuli based responses which defend against pathogentic... -
The effect of bilayer rigidity on the interactions with perfluoroalkyl compounds
Perfluoroalkyl substances (PFASs) are used extensively in industrial products although have been identified as emerging pollutants accumulating in wildlife and environment.... -
An investigation on the adsorption of reverse pluronic and additives on metal...
PPO-PEO-PPO copolymer-based lubricant with extreme pressure or friction modifier additives has been introduced as boundary lubricant in metal forming. The Pluronic reverse... -
Neutron reflectivity study on sefl-repairing polymer brushes by surface segre...
We have recently studied the surface segregations of amphiphilic block copolymers blended in a matrix of cross-linked poly(dimethyl siloxane). In this system, while the... -
Evidence for a Diffuse Interfacial Region at the Dichloroethane/Water Interface
The 1,2- dichloroethane (DCE)/water interface is important because of its suitability as an electrochemical interface between two immiscible electrolyte soloutions. An issue of... -
Surfactant Segregation in Plasticised PVA
PVA film is widely used as a non-toxic water soluble polymer. This proposal relates to its use in unit dose detergent pouches where plasticised PVA film stores a concentrated... -
The hydration and ordering of lamellar block copolymer films prior to the for...
The key to the use of polymer vesicles as effective molecular delivery systems is in the ability to efficiently encapsulate a molecular payload within the vesicle. We would like... -
Dynamic Nuclear Polarization in GaAs by electrical spin injection
We propose to measure the dynamic nuclear polarization in a GaAs-based structure caused by electrical injection of a spin-polarized current using polarized neutron... -
Impact of Elasticity on Surface Wetting
We have recently characterised a surface wetting transition for a low molecular weight oligomer in a high molecular weight rubbery polymer. Although weak surface segregation of... -
Effect of alkyl chain length on the adsorption of n-alkyl phosphocholine surf...
This proposal relates to the study of adsorption of n-dodecyl phosphocholine (C12PC) at the oil-water interface. The thickness of the adsorbed monolayers measured for dC12hPC... -
Surface activity of fluoroblock copolymers in model marine coatings
Marine coatings are commonly based on silicone polymers, which have a low surface energy and a degree of deformability which contribute to release of marine fouling species. Low... -
Interaction of thermo-responsive deutrated nanogels with lipid monolayer at t...
Drug delivery through skin is an important delivery route. However, the outermost layer of the skin provides a formidable barrier to dermal absorption and penetration for... -
Aquatic Methane Adsorption and Desorption on Minerals
In this project we propose to study the adsorption of methane onto a model mineral surface. This type of study is crucial to the understanding of the temperature dependence of... -
Influence of Mg insert layers on interface magnetism in crystalline CoFe(B)/M...
We plan to continue our previous investigation on the influence of thin Mg insert layers on magnetism at buried interfaces in structures that model the lower electrode/barrier... -
Novel block bottlebrush polyelectrolytes: The effect of cationic block charge...
In this work we will study a novel block copolymers consisting of a linear cationic block and uncharged bottle-brush block having 45 units long poly(ethylene oxide) side chains....