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Structural study of oxygen ion conduction in microporous Mayenite
The crystal unit cell of mayenite, 12CaO.7Al2O3, consists of a cubic lattice of [Ca24Al28O64]4+ with the remaining 2*O2- contained in cages, which are linked by channels within... -
Temperature induced structural phase transitions in BaPrO3 and acceptor doped...
The sequence of structural phase transitions that occur in distorted ABO3 perovskites as a function of temperature is of intrinsic interest for better understanding of the... -
Investigation of giant crystal electric field (CEF) splitting in CeIr3Si2
CeIr3Si2 exhibits highly anisotropic bulk properties with two magnetic transitions at TN1 ~ 3.9 K and TN2 ~ 3.1 K. The overall CEF splitting of the J=5/2 ground multiplet of... -
Defect Structure in Lead Doped Bismuth Yttrates
Stabilised bismuth oxides are of interest as intermediate temperature solid electrolytes for a variety of electrochemical device applications. Lead doping into bismuth yttrate... -
The ground state of a Kondo ion: V dissolved in the noble metal Au.
The 'non-magnetic' ground state of a Kondo ion is generally believed to consist of the localised spin surrounded by a compensating cloud of conduction electrons coupled...