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Kinetics of Benzene Hydrogenation Revisited in the Presence of Excess Liquid
Heterogeneous catalysis, where the reagents are either contained in a liquid medium, or are liquids in their own right, plays a significant part of the chemical industry. These... -
Dipolar frustration on the triangular lattice: Order and disorder in AgNCO
We propose to use neutron total scattering to characterise isocyanate (NCO-) orientations within the orientationally-disordered phase of AgNCO. The arrangement of NCO- ions in... -
Low Temperature Magnetic Structure of Doped Iridate Sr2Ir0.5Rh0.5O4
There is a significant interest in the electronic and magnetic properties of the layered iridates owing to the variety of potential exotic phases of matter they exhibit. In... -
Kinetics of Benzene Hydrogenation Revisited in the Presence of Excess Liquid
Heterogeneous catalysis, where the reagents are either contained in a liquid medium, or are liquids in their own right, plays a significant part of the chemical industry. These... -
Determination of the bondlength of the surface hydride in PdH
Supported palladium particles are used as catalysts in many processes. In the course of investigation of Pd-based catalysts used for the selective hydrogenation of nitro-arenes... -
Highly selective adsorptive SMOFs
In the area of metal-organic porous materials, supramolecular metal-organic frameworks (SMOFs) constitute a blooming alternative. Their examples are still relatively scarce when... -
A Study of AuMu^+ Final States by Dia RF Resonance
Small-sized metal nanoparticles (NPs) are of long standing interest to both magnetism and heterogeneous catalysis. Muon studies of Au NPs encapsulated in 'SBA-15' silica are... -
Local structure, dynamics and magnetism of the phases of cobalt imidazolate
This proposal concerns the metal-organic framework (MOF), cobalt imidazolate. Imidazole (im) is a small, flat organic molecule that forms slightly bent metal-im-metal linkages,... -
Kinetics of Hydrogen Abstraction in Butane by Mu Reactivity
Hydrogen abstraction reactions are key steps in free radical mechanisms that dominate the combustion and atmospheric chemistry of the alkane hydrocarbons and, as such, merit... -
Determination of nuclear quantum effects on the hydrogen adsorption in metal-...
Metal-organic frameworks represent one of the most studied options to store hydrogen for clean-energy applications. Nuclear quantum effects, and in particular zero-point... -
Hydrogen loading and unloading kinetics in thin Mg films
Hydrogen storage in metal hydrides has recently been studied as a possible way to store energy. One of the possible options is magnesium, which is abundant and cheap and it has... -
Magnetic structure of the potential multiferroic GdCrO3
Because of the potential applications of multiferroicity, the discovery of a new multiferroic (MF) material is invariably met with great enthusiasm in the condensed matter... -
Study of the S(Q, w) map of propane/propene adsorbed on non-charged ITQ-29 Ze...
Zeolites are perhaps the most successful microporous materials used for catalysis and separation processes in refineries and chemical industries[1-3]. This is due to the... -
The chemisorption of hydrogen over a high surface area cobalt catalyst: An IN...
In collaboration with Sasol Technology UK Ltd, the research team have previously used INS to investigate the surface chemistry of synthesis gas (CO + H2) over a series of... -
Investigation of pseudo-condensation of supercritical H2 in nanoporous hydrog...
This proposal aims to use small angle neutron scattering for characterization of hydrogen adsorption (including the provision of a quantitative value for the absolute hydrogen... -
The Dynamics of Breathing Metal-Organic Frameworks from Total Scattering
Metal-organic framework materials are a topical family of nanoporous solids that have potential applications in molecular storage, separation and catalysis. Some of these... -
Host-guest interactions in flexible SMOFs
In the area of metal-organic porous materials, supramolecular metal-organic frameworks (SMOFs) constitute a blooming alternative. Their examples are still scarce when compared... -
Proton mobility in hydrated melanin as a function of temperature
Electroceuticals is the attempt to speak the electrical language of the nerves to achieve higher treatment effect. Thus, the search is on to develop devices to enhance... -
Probing the influence of deposition energy on the magnetic properties of FeCo...
Magnetic HEA thin films could open up the possibility to develop spintronic devices for use in hostile environments e.g. for high temperature applications. Previous studies have... -
Cavitation processes in gas desorption experiments.
The aim of the experiment is to improve understanding of the onset of the cavitation process in desorption, in order to, ultimately, better understand adsorbate behaviour and...