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Effects of Architecture on Polymer Diffusion
As part of a wider study we are studying the effects of polymer architecture between cyclic and linear polymers. From ATR-FTIR measurements we observe clear differences between... -
Characterisation of bioadhesive protein-PEG conjugates grafted to titanium su...
Summary: Titanium implants are surgically important and require a hydrophilic polymer coating to prevent biofouling in situ. Bioadhesive proteins can be covalently tethered to... -
Effects of Architecture on Polymer Diffusion
As part of a wider study we are investigating the effects of polymer architecture between cyclic and linear polymers. From ATR-FTIR measurements we observe clear differences... -
Neutron Reflectometry of Tethered Microphase Separated Block Copolymers
Neutron reflectometry will be used to probe the scattering length density profile in tethered films of block copolymers grafted onto silicon substrates. The tethered... -
Surface structures of polycations in confined geometries
A second-generation surface force style apparatus has been developed to probe the inter-surface and near-surface structures under compressive forces. Systems of current academic... -
Basic Science for Offpsec : Part 2
This proposal is part 2 of a set of two proposals on Offspec aimed at understanding some of the effects seen in off-specular data and in particular the use of the spin echo... -
Core-Shell Melt Electrospun Fibres
Electrospinning is a technique that produces nanoscale to microscale sized polymer fibre from solution and the molten state. We have previously used small angle neutron... -
Investigating dental resin polymer structures of as a function of light-curin...
Dimethacrylate resins are currently used for dental fillings. The polymers are set by free radical polymerisation. At present light curing protocols require 40s exposure at... -
Conformation of thermo-responsive methacrylate based comb polymers in D2O sol...
A series of well defined comb polymers consisting of methacrylate backbones and oligo(2-ethyl-2-oxazoline) side chains was shown to exhibit lower critical solution temperature... -
Interactions between a polymer brush grown from a macro-initiator-modified sa...
We propose to make neutron reflectivity measurements of the weak polyelectrolyte, poly(dimethy amino ethyl methacrylate), grown from two different surface densities of initiator... -
Dynamics of Polymer/Polymer nanocomposites
By adding only about 1% of soft polymer nanoparticles to natural rubber, a dramatic decrease in the viscosity (more than 50%) is induced. Our recent time of flight measurements... -
Voltage-induced swelling and collapse of weak polyelectrolyte brushes
The voltage-induced actuation of a weak polyelectrolyte brush is an example of an ultrathin, remotely controlled responsive surface coating. We propose a continuation of... -
Is dynamic asymmetry the essential ingredient in the (universal?) 'strong-fra...
We want to elucidate whether the so-called ¿strong-fragile¿ transition reported for water mixtures is a universal phenomenon driven by confinement effects originated by the... -
Has residual solvent an impact on the dynamics of PMMA ultra thin films?
Polymeric films thinner than a 100 nm exhibits a variation of the glass transition temperature of a few tens of degrees and can brake up into discrete islands when heated near...