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Determination of the structure of methoxy on eta-alumina
We have recently demonstrated that we are able to obtain structural information about adsorbed hydrogenous species from a variety of metal catalysts. We emphasise that this is a... -
Defect perturbation of the rotational states of NH4 in octahedral environments
The (NH4)0.02 Rbx K0.98-x I system offers advantages for the systematic study of tunnelling species and how they interact. Currently there are two models to explain the dynamics... -
The use of INS to characterise prototype methane reforming catalysts over a r...
Previous work by the experimental team has successfully examined methane reforming catalysts using CO2 as the oxidant. Unfortunately, the progression to using steam as the... -
High resolution INS spectra of hydrocarbonaceous overlayers formed on novel m...
For the first time, the research team aim to use INS to characterise a series of new high specification methane reforming catalysts. The enhanced performance of these catalysts... -
Study of carbon supports for catalysts used in the direct synthesis of hydrog...
We have recently shown that acid washing of a carbon support prior to metal (Au, Pd) deposition enhances the activity of the resulting catalysts for the direct synthesis of... -
Negative thermal expansion in ReO3: anomalous variation with temperature
ReO3 is a well-known oxide framework with unusual thermal expansion behaviour, exhibiting multiple regions of both positive and negative thermal expansion (NTE). We propose to... -
INS studies of Nafion and model compounds
In the archetypal hydrogenoxygen proton exchange membrane fuel cell design, a proton-conducting polymer membrane (typically Nafion) contains the electrolyte solution that... -
Probing the role of Mo on the precipitation kinetics of nanoscale titanium ca...
Ever more stringent environmental regulations have driven the automotive industry to strive for light weight solutions in automotive body and chassis applications, without... -
Copy of: Characterization of Indo-Persian blades of the Wallace Collection
This experiment is a continuation of a previous one aiming to analyse the composition and microstructure of Indo-Persian swords and daggers of the Wallace Collection whose... -
The adsorption of methyl proprionate on silica catalysts.
Commercial routes for the manufacture of methyl methacrylate monomer have recently been developed that involve the reaction of esters over modified silicas, which are amphoteric... -
The application of INS to investigate the active phase of methane steam refor...
A previous allocation of beamtime on MAPS [RB720354] revealed the vibrational fingerprint of methane reforming catalysts operating under so-called ¿dry¿ reforming conditions.... -
Investigation of magnetic defects in exfoliated graphite
Graphene has recently received widespread attention, after the discovery of its stability as a 2Dcrystal at ambient conditions and thanks to a wealth of possible applications.... -
Texture memory and variant selection for steel and titanium and zirconium alloys
The proposed experiment will focus on determining the level of texture memory and variant selection on both heating and cooling for steel and titanium and zirconium alloys with... -
The structural phase transitions of Ammonia Borane, an invetigation of the dy...
Ammonia Borane (AB), NH3BH3, was first synthesised in the 1950s and has now become the focus of a world wide research program with regards to its potential as a hydrogen store.... -
The expoitation of the A, B, C spectral signatures of H-bonds.
Intermediate strength hydrogen bonds, H-bonds, are known to play a role in the reactions of surface bound species, especially on the widely used industrial substrate... -
The use of INS to characterise deactivation of methane reforming catalysts.
For the first time, the research team aim to use INS to characterise a series of candidate methane reforming catalysts. Recent studies have shown that modification of... -
The chemisorption of hydrogen over a Raney cobalt catalyst: An INS investigation
Building on a successful programme investigating aspects of iron based Fischer-Tropsch synthesis (FTS) catalysts, it is opportune to extend that work to include Co FTS...
