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Study of cooperative aggregation of organic semiconductor in solution
Soluble pentacene derivatives are high performing semiconductors for use in organic transistors offering low cost solution processability, and potential for migration to... -
Study of macromolecular configuration of P3HT and P3HS in solution by SANS me...
The possibility of low-cost roll to roll fabrication procedures of organic solar cells using poly-3-hexyl-thiophene (P3OT) solutions has attracted intensive research in order to... -
Characterization of P3HT:PCBM blends by SANS measurements
Blends of poly-3-hexyl-thiophene (P3HT) and 6,6-phenyl-C61 butyric acid methyl ester (PCBM) are the most promising candidates for active layers of plastic solar cells with high... -
Wittig Reaction: Cleaning up 50 years of Waste in Metal-Free Catalysis
Our recent works have solved a 50 yr old problem (in part) with computational steering successfully guiding synthetic work towards a wittig process catalytic in phosphine. The... -
Inelastic neutron scattering of alpha and beta anomers of xylose and glucose:...
Carbohydrates are one of the major classes of biomolecules that make up most of the organic matter on earth and serve as energy stores, fuels and metabolitic intermediates. They... -
Higher resolution inspection of the hydrocarbon pool connected with the metha...
The reaction of methanol to form hydrocarbons over zeolite catalysts is an important option for conversion of natural gas or coal to liquid fuels. We have shown previously via... -
Magnetic excitations in mesoporous hematite
We have recently prepared mesoporous forms of various metals oxides. In some cases the imposition of a mesostructure changes other properties of the material significantly. One... -
Degree of Host-Guest Molecular Interactions from Nanoscale Confinement of Dru...
The nanoscale pores in metal-organic frameworks (MOFs) can be exploited to confine small molecular guests to yield Guest@MOF composite systems. One interesting avenue is to... -
INS studies of the interaction of propene with ZSM-5
Fluidised Catalytic Cracking (FCC) units are one of the major conversion units in modern petrochemical refineries. ZSM-5 additives are used in FCC units to convert gasoline... -
Investigating the diffusion component of the toluene hydrogenation reaction i...
The diffusion of hydrocarbons relevant to the toluene hydrogenation reaction will be measured both as unconfined liquids and confined in the catalyst Pt/MCM-41. Diffusion will... -
Emission Enhancing Micelles and Microemulsions for the Analytical Sciences
Nuclear power has played an important role in Britain¿s history and is set to play an equally important role in its future. We have recently established a network involving... -
Investigating methods to create cavities within templated electrodeposited po...
Nanoporous membranes are widely used in (bio)sensors, chromatography, charge storage devices, filtration and catalysis. With increasing efforts to develop microfabricated sytem-... -
Surface charge induced layering of ionic liquids on mica
The structure of ionic liquids at charged interfaces is an exciting and vibrant area of current research. Previous surface force apparatus experiments have shown layering up to... -
Evolving microemulsions - tuning selectivity in oxidation reactions
We have begun to explore the synthesis, reactivity and physicochemical properties of a number of surface-active metal complexes, to devise a method for the catalytic... -
Structure of Petroleum Asphaltenes in Solution
Asphaltenes are the heaviest end of crude oil and are responsible for a multitude of engineering challenges. They can precipitate from the oil, depositing, blocking pipelines... -
Investigation of asphaltene nanoaggregate size under conditions of CO2 reserv...
The asphaltene fraction of crude oil is defined by its solubility parameters (insoluble in n-heptanebut soluble in toluene). Changes in conditions (temperature, pressure,... -
Co-existing Hydro/Fluorcarbon Microemulsions for Lanathanide Emission Enhance...
Very recently (April) we undertook a SANS experiment (RB1110147) to probe the partitioning of metal-acac ligand complexes in complex microemulsion media. Our aim was to design a... -
The structure of mucin at large distances - a spin-echo SANS study
Mucus is a bio-gel, an opaque and slimy secretion that forms a continuous ¿blanket¿ adherent to epithelial surfaces in mammalian organs (eye, nose, conductive airways,... -
Contrast match on activated carbon: density and structure determination
At present there is a growing interest to porous carbon due to its large field of application. Porous activated carbons with their large surface area and microporosity are one... -
SANS study of self assembled structures formed from salicylate surfactant in ...
We wish to determine a structure we have observed in a dodecane/surfactant/water system. Initial experimentation has suggested the possibility of spontaneous formation of a...