Geochemistry and stable carbon isotope composition of kerogen of DSDP Site 124-767

DOI

Celebes Basin sediments from Ocean Drilling Program Site 767 (Leg 124) containing both marine and terrestrial organic matter have been investigated through palynofacies and geochemical analyses. The main degradation processes affecting or having affected organic matter are recorded in the sedimentary column as shown by ammonium, phosphate and sulfate pore-water profiles, and by petrographic and geochemical analyses of sediments.In the upper part of the sedimentary section (down to 200 mbsf), the decrease of the ratio of total organic carbon to sulfur (TOC/S) with depth, generally related to the sulfate reduction process, is accompanied by an increase of framboidal pyrite content in the marine organic matter, and by an increasing amount of amorphous marine organic matter relative to the total organic matter. However, as the terrestrial organic input also varies with depth, dilution effects are superimposed on diagenesis. This continental supply affects the TOC/S ratio by increasing total organic carbon and decreasing the ability of the bulk organic matter to be metabolized through sulfate reduction. A positive relationship between the TOC/P ratio and the amount of degraded organic matter of marine origin clearly displays the effect of an organic source on the composition of the sediment. Each lithostratigraphic unit possesses its own characteristics in terms of composition and preservation of organic matter. The effects of diagenesis can only be appreciated within a single lithostratigraphic unit and mainly affect the less-resistant marine organic matter.

Supplement to: Lallier-Verges, Elisabeth; Bertrand, Philippe; Desprairies, Alain; Berner, Ulrich (1991): Geochemical and optical investigations on degradation processes affecting organic matter in Celebes Basin sediments. In: Silver, EA; Rangin, C; von Breymann, MT; et al. (eds.), Proceedings of the Ocean Drilling Program, Scientific Results, College Station, TX (Ocean Drilling Program), 124, 239-247

Identifier
DOI https://doi.org/10.1594/PANGAEA.762060
Related Identifier IsSupplementTo https://doi.org/10.2973/odp.proc.sr.124.179.1991
Metadata Access https://ws.pangaea.de/oai/provider?verb=GetRecord&metadataPrefix=datacite4&identifier=oai:pangaea.de:doi:10.1594/PANGAEA.762060
Provenance
Creator Lallier-Verges, Elisabeth; Bertrand, Philippe; Desprairies, Alain; Berner, Ulrich
Publisher PANGAEA
Publication Year 1991
Rights Creative Commons Attribution 3.0 Unported; https://creativecommons.org/licenses/by/3.0/
OpenAccess true
Representation
Resource Type Supplementary Publication Series of Datasets; Collection
Format application/zip
Size 2 datasets
Discipline Earth System Research
Spatial Coverage (123.503W, 4.791S, 123.503E, 4.792N); Mindanao Sea
Temporal Coverage Begin 1988-11-09T21:15:00Z
Temporal Coverage End 1988-11-19T20:15:00Z