(Aza)Pentacenes Clipped into a Ring: Stabilization of Large (Aza)Acenes [data]


A doubly alkylene bridged 6,13-diphenylpentacene and analogously bridged azapentacenes were prepared; they are persistent. The doubly bridged azapentacenes display superior photochemical, oxidative and thermal stabilities compared to azapentacenes protected by bis(TIPS-ethynyl)-substituents—clipping an azaacene into a large ring is a viable complement in stabilization.

Dataset contains raw data related to synthesis and characterization of the reported compounds of the related publication.

DOI https://doi.org/10.11588/data/5VN0H0
Related Identifier IsCitedBy https://doi.org/10.1002/anie.202015348
Metadata Access https://heidata.uni-heidelberg.de/oai?verb=GetRecord&metadataPrefix=oai_datacite&identifier=doi:10.11588/data/5VN0H0
Creator Ahrens, Lukas ORCID logo; Tverskoy, Olena; Weigold, Svenja ORCID logo; Ganschow, Michael; Rominger, Frank; Freudenberg, Jan (ORCID: 0000-0003-0998-693X); Bunz, Uwe H. F. ORCID logo
Publisher heiDATA
Contributor Bunz, Uwe; heiDATA: Heidelberg Research Data Repository
Publication Year 2024
Funding Reference Deutsche Forschungsgemeinschaft (DFG) SFB 1249 ; Studienstiftung des Deutschen Volkes
Rights CC BY 4.0; info:eu-repo/semantics/openAccess; http://creativecommons.org/licenses/by/4.0
OpenAccess true
Contact Bunz, Uwe (Heidelberg University, OCI)
Resource Type Dataset
Format application/zip
Size 5822657; 1156955; 1781629; 210548736; 28994455; 1776181
Version 1.0
Discipline Chemistry; Natural Sciences