Chemical composition of manganese deposits (Birnessite) from Scotland

DOI

A manganese pan near Birness contains grains of an optically uniaxial negative mineral near (Na0.7Ca0.3)Mn7O14·2·8H2O, giving an X-ray powder pattern similar to that of synthetic materials described as 'manganous manganite' and delta-MnO2. Material giving a similar pattern has been described from a natural occurrence in Canada, but no mineral name was assigned; the name birnessite is now proposed. The mineral is probably formed by air-oxidation of manganous oxides under alkaline conditions.

Grains (up to 4x8x3 mm.) removed from the crust and ground to a fine powder (200-mesh IMM sieve) for analysis.From 1983 until 1989 NOAA-NCEI compiled the NOAA-MMS Marine Minerals Geochemical Database from journal articles, technical reports and unpublished sources from other institutions. At the time it was the most extended data compilation on ferromanganese deposits world wide. Initially published in a proprietary format incompatible with present day standards it was jointly decided by AWI and NOAA to transcribe this legacy data into PANGAEA. This transfer is augmented by a careful checking of the original sources when available and the encoding of ancillary information (sample description, method of analysis..) not present in the NOAA-MMS database.

Supplement to: Jones, L H P; Milne, Angela A (1956): Birnessite, a new manganese oxide mineral from Aberdeenshire, Scotland. Mineralogical Magazine, 31(235), 283-288

Identifier
DOI https://doi.org/10.1594/PANGAEA.867326
Related Identifier IsSupplementTo https://doi.org/10.1180/minmag.1956.031.235.01
Related Identifier IsDerivedFrom https://doi.org/10.7289/V52Z13FT
Related Identifier IsDocumentedBy https://doi.org/10.7289/V53X84KN
Metadata Access https://ws.pangaea.de/oai/provider?verb=GetRecord&metadataPrefix=datacite4&identifier=oai:pangaea.de:doi:10.1594/PANGAEA.867326
Provenance
Creator Jones, L H P; Milne, Angela A
Publisher PANGAEA
Publication Year 1956
Rights Creative Commons Attribution 3.0 Unported; https://creativecommons.org/licenses/by/3.0/
OpenAccess true
Representation
Resource Type Supplementary Dataset; Dataset
Format text/tab-separated-values
Size 14 data points
Discipline Earth System Research
Spatial Coverage (-1.993 LON, 57.403 LAT); Scotland