Anion order in perovskite oxynitrides

DOI

Transition metal oxynitrides with perovskite type structures are an emerging class of materials with optical, photocatalytic, dielectric and magnetoresistive properties that may be sensitive to oxide/nitride order, but the anion ordering principles have been unclear. We recently studied the representative compounds SrMO2N (M = Nb, Ta) using neutron (D2B@ILL) and electron diffraction data. This revealed a robust partial anion order in high temperature pseudo-cubic phases, which directs the rotations of MO4N2 octahedra in room temperature superstructures. We propose here to study SrTaO2N and two related Ta oxynitride perovskites to higher temperatures, ~1200 C to establish whether a transition to a truly cubic phase occurs and to confirm and extend the recently discovered principles.

Identifier
DOI https://doi.org/10.5286/ISIS.E.24086380
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/24086380
Provenance
Creator Dr Lucy Clark; Professor Paul Attfield; Dr Judith Oro Sole; Mr Wei-Ting Chen; Professor Amparo Fuertes; Dr Angel Arevalo Lopez
Publisher ISIS Neutron and Muon Source
Publication Year 2014
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Photon- and Neutron Geosciences
Temporal Coverage Begin 2011-07-18T05:45:09Z
Temporal Coverage End 2011-07-21T05:38:28Z