Alcohols in Cationic Surfactant Micelle Solutions

DOI

This proposal continues our studies of water and small molecule binding around surfactant micelles using NIMROD, to obtain previously inaccessible details of their molecular interactions. Here we wish to study the effect of addition of small amounts of alcohols to the micellar solutions. Alcohols such as methanol and ethanol are typically generated by inorganic precursors, such as tetramethoxysilane, during the templating reaction with micelles used to form surfactant-templated mesoporous silicas. Alcohols have been implicated in altering the structure formed during templating since, for instance, different pore geometries are formed when the precursor generates ethanol vs methanol. Thus here we propose to study the alcohol-micelle structures for a series of short chain alcohols at ratios equivalent to those found in templated silica syntheses.

Identifier
DOI https://doi.org/10.5286/ISIS.E.60998568
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/60998568
Provenance
Creator Dr Daniel Bowron; Dr Emelie Nilsson; Professor Viveka Alfredsson; Professor Karen Edler
Publisher ISIS Neutron and Muon Source
Publication Year 2018
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Natural Sciences
Temporal Coverage Begin 2015-06-11T08:00:00Z
Temporal Coverage End 2015-06-15T15:28:34Z