How Encapsulated is a Sodide? Li+Na--EtNH2 vs Li+e--EtNH2

DOI

We have recently begun to look at how large, polarisable alkalides (group 1 metal anions) are solvated in solution. This proposal aims to determine how ethylamine is able to cosolvate a sodide in the presence of lithium, and determine whether there is a long-range liquid structure as found in the case of methylamine. We will directly compare this with the analogous solvated electron system, using a combination of neutron scattering, ab initio molecular dynamics and empirical potential structure refinement.

Identifier
DOI https://doi.org/10.5286/ISIS.E.RB1920129-1
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/105600105
Provenance
Creator Dr Neal Skipper; Dr Andrew Seel; Dr Sabrina Gaertner; Dr Nicole Holzmann; Dr Silvia Imberti; Mr Thomas Nicholas; Dr Tom Headen
Publisher ISIS Neutron and Muon Source
Publication Year 2022
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Natural Sciences; Physics
Temporal Coverage Begin 2019-09-19T07:30:00Z
Temporal Coverage End 2019-09-25T08:18:19Z