Low-energy dynamics and emergent excitations in the cubic NTE material Cd(CN)2

DOI

Cadmium cyanide is a negative thermal expansion material: it shrinks – rather than expands – when heated. We are proposing to carry out an inelastic neutron scattering experiment on the MARI spectrometer. This experiment will allow us to work out exactly how the structure of cadmium cyanide responds to temperature. We are trying to answer the question: when the material is heated, how do its atoms vibrate? Answering this will allow us to work out the mechanism responsible for its negative thermal expansion effect. This question might have been asked (and answered) many years ago, were it not for the fact that cadmium absorbs neutrons incredibly strongly. What's changed is that we now have access to a sample made from a single isotope of cadmium that is actually a good neutron scatterer, rather than a good neutron absorber.

Identifier
DOI https://doi.org/10.5286/ISIS.E.RB1920076-1
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/105600830
Provenance
Creator Dr Anthony Phillips; Dr Chloe Coates; Professor Andrew Goodwin; Mr Johnathan Bulled; Dr Helen Walker; Dr Arianna Minelli
Publisher ISIS Neutron and Muon Source
Publication Year 2022
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Natural Sciences
Temporal Coverage Begin 2019-10-04T07:30:00Z
Temporal Coverage End 2019-10-10T07:18:52Z