Following the formation of Ho2Ge2O7 pyrochlore using high-pressure neutron diffraction

DOI

When synthesised at high pressure and temperature, holmium germanate adopts the pyrochlore structure. Because of its geometry, materials with this structure often have exotic and interesting magnetic properties. Normally, the pyrochlore structure is only stable when the two metals are relatively similar in size, which is not the case for Ho and Ge. This explains why extreme conditions are required to make it. In this experiment we will use the Pearl diffractometer to follow the conversion of a mixture of the simple component oxides to the pyrochlore as we increase temperature and pressure. We have also recently made a sample of holmium germanate in a different crystal structure and hope to use this as a precursor phase that can be converted to the pyrochlore at lower temperature or pressure than the simple oxide approach.

Identifier
DOI https://doi.org/10.5286/ISIS.E.61000343
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/61000343
Provenance
Creator Dr Helen Playford; Professor Richard Walton; Dr Craig Bull; Dr Matthew Tucker
Publisher ISIS Neutron and Muon Source
Publication Year 2018
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Natural Sciences
Temporal Coverage Begin 2015-06-20T09:00:00Z
Temporal Coverage End 2015-06-25T16:00:00Z