Phase behaviour of methane clathrate under conditions relevant to Titan's interior

DOI

Methane clathrates are likely to be an important constituent of icy satellite interiors and a source of methane in the atmosphere of Saturn's giant satellite Titan. There is uncertainty concerning the phase behaviour of this material under the pressures which exist in Titan's interior. At room temperature, the primitive cubic low-pressure phase is though to transform to a hexagonal structure at ~ 1 GPa, and thence to an orthorhombic phase, which is a stuffed form of cubic ice, at ~ 3 GPa. However, there is evidence that the sequence is interrupted by the occurrence of a fcc phase prior to the hexagonal phase at temperatures close to the dissociation curve. Our objective is to compress methane clathrate both at room T and near to the dissociation curve in order to establish the definitive sequence of phase changes, and to obtain P-V data on those phases.

Identifier
DOI https://doi.org/10.5286/ISIS.E.RB1110043-1
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/24088871
Provenance
Creator Professor Ian Wood; Dr Dominic Fortes; Mrs Gillian Sclater; Dr Ian Crawford; Professor David Price
Publisher ISIS Neutron and Muon Source
Publication Year 2015
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Photon- and Neutron Geosciences
Temporal Coverage Begin 2012-06-07T10:28:01Z
Temporal Coverage End 2012-06-11T08:20:07Z