Structural characterization of a fully detuterated manganese Prussian Blue analogue

DOI

The aim of this proposal is to perform a neutron diffraction determination of the first perdeuterated Mn-Prussian Blue (PB) analogue of composition: Mn(II)3 [Mn(III)(CN)6]2 ¿(D2O)6.xD2O (x = 6-10) . Air-stable, cubic crystals of ~1.5 mm edges suitable for measurements on the instrument SXD, have been recently obtained by in-gel crystallization. A preliminary characterization has shown a magnetic ordering temperature around 30K, therefore we ask for a total of 8 days of beamtime on SXD in order to determine the structure of this compound at 50 and at 15K, i.e. above and below the magnetic transition.

Identifier
DOI https://doi.org/10.5286/ISIS.E.60595597
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/60595597
Provenance
Creator Professor Hans-Beat Buergi; Dr Silvia Capelli; Dr Dmitry Chernishov
Publisher ISIS Neutron and Muon Source
Publication Year 2018
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Natural Sciences; Physics
Temporal Coverage Begin 2015-04-27T09:00:00Z
Temporal Coverage End 2015-05-01T09:00:00Z