Spin dynamics in CP*-Ho-COT

DOI

Single-Molecular Magnets (SMMs) provide access to the mesoscopic world. They possess slow magnetization relaxation due to an energy barrier induced by axial magnetic anisotropy, which makes them potential candidates for quantum computing, high-density storage and magnetic refrigeration. It is essential to improve blocking temperatures and control of quantum effects in SMMs for such applications. Zadrozny suggested that the magnetization relaxation in SMMs is governed by four processes (direct, quantum tunnelling (QT), Raman and Orbach), but how they differ has not been studied in a series of closely related materials, and importantly, the role of correlations has not been investigated. We propose to investigate the spin fluctuations and correlations in members of the CP*-Ho-COT series at high temperatures to address this.

Identifier
DOI https://doi.org/10.5286/ISIS.E.92923482
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/92923482
Provenance
Creator Mr Zhengqiang Yang; Dr Sean Giblin; Miss Shuo Han; Professor Bingwu Wang; Dr Anthony Phillips; Miss QIONG YUAN; Professor Alan Drew; Dr Peter Baker; Mr Yin-Shan Meng; Dr Koji Yokoyama; Dr Francis Pratt; Mr Anders Jensen
Publisher ISIS Neutron and Muon Source
Publication Year 2021
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Photon- and Neutron Geosciences
Temporal Coverage Begin 2018-04-23T08:30:00Z
Temporal Coverage End 2018-04-25T08:38:26Z