Anomalous elasticity in negative thermal expansion materials

DOI

Recent experimental work on the negative thermal expansion material Zn(CN)2 has shown that the elastic stiffness is anomalously reduced on compression. That is, if B is the bulk modulus, the derivative dB/dP is negative. From our molecular dynamics simulations of this system we have predicted that the dB/dP has a striking temperature-dependence, namely with positive value at low temperature, then quickly falling to a maximal negative value before slowly tending towards zero at high temperature. The purpose of this proposal is to test this prediction using powder diffraction and performing measurements across the two-dimensional space of both pressure and temperature. The experiment will be performed on Polaris using the gas cell pressure device within a cryostat.

Identifier
DOI https://doi.org/10.5286/ISIS.E.24089650
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/24089650
Provenance
Creator Professor Andrew Goodwin; Mr Hong Fang; Professor Martin Dove; Dr Anthony Phillips; Dr Matthew Tucker
Publisher ISIS Neutron and Muon Source
Publication Year 2015
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Photon- and Neutron Geosciences
Temporal Coverage Begin 2012-10-12T09:54:33Z
Temporal Coverage End 2012-10-16T05:51:11Z