STRUCTURAL DYNAMICS IN MgCl2-BASED ZIEGLER-NATTA CATALYSTS

DOI

The proposal aims at revisiting the properties of disordered, nano-sized and structurally dynamic delta-MgCl2 particles as fundamental components of Ziegler-Natta (ZN) catalysts for olefin polymerization. Inelastic Neutron Scattering (INS) technique, coupled with advanced theoretical calculations, is expected to provide information on the atomic dynamics of MgCl2-based catalysts, in strong synergy with what obtainable from Raman and IR spectroscopies at UniTO. The proposal, motivated by a strong industrial interest within the DPI 2.0 programme (industrial funding partners: Borealis, Braskem, ExxonMobil, Reliance, SABIC, SCG Chemicals and Sinopec) and written in close synergy with our Japanese partners (T. Taniike’s group, JAIST), stands up as a pioneering INS investigation on MgCl2 systems and as such may have a very high potential impact in the scientific community.

Identifier
DOI https://doi.org/10.5286/ISIS.E.92918326
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/92918326
Provenance
Creator Miss Eleonora Vottero; Dr Svemir Rudic; Professor Elena Groppo; Dr Andrea Piovano; Dr C Lamberti; Dr Alessandro Piovano
Publisher ISIS Neutron and Muon Source
Publication Year 2021
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Natural Sciences
Temporal Coverage Begin 2018-04-20T08:00:00Z
Temporal Coverage End 2018-04-25T14:40:03Z