Observation of intermediates on a transfer hydrogenation catalyst

DOI

The design and development of novel catalysts for chemical synthesis is incredibly important from both academic and industrial perspectives. Approximately 90 % of all commercial chemical processes invoke the use of a catalyst, which can be utilized to reduce the energy demands and waste generated. Transfer hydrogenation reactions are a fantastic example of how modern catalyst design can be used to improve atomic efficiency in chemical synthesis. We have developed a highly efficient novel heterogeneous catalyst which is highly active and selective for the production of a biofuel (gamma-valerolactone) from a biomass feedstock (methyl levulinate) via transfer hydrogenation. With the use of the facilities at ISIS, we hope to gain a greater understanding of why this material is such a good catalyst for this reaction and hope this work will act as a foundation for future research in this area.

Identifier
DOI https://doi.org/10.5286/ISIS.E.98019577
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/98019577
Provenance
Creator Professor Stewart Parker; Professor Graham Hutchings; Dr John Mark Douthwaite; Dr Sarwat Iqbal; Dr David Willock
Publisher ISIS Neutron and Muon Source
Publication Year 2021
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Natural Sciences
Temporal Coverage Begin 2018-10-14T07:00:00Z
Temporal Coverage End 2018-10-18T07:00:00Z