58 datasets found

W I F David - Energy Project

We request a total of 9 days on TOSCA:6 days to investigate the interactions exhibited by two Li containing metal-organic framework materials on loading with CO2. Doping of Li...

Given its high hydrogen gravimetric density, ammonia may be utilised as a hydrogen carrier, and thus ammonia stores are an area of interest. It is known that Mg(BH4)2 takes up...

We propose to investigate the detailed spectroscopy of the expanded metal systems 7Li(NH3)4 and 7Li(ND3)4 by inelastic neutron scattering. 7Li(NH3)4 shows multiple phase...

We request 3 days on TOSCA to study molecular rotations of NH4+ and BH4- ions and the ionic disorder in ammonium borohydride (rock salt lattice) and its methylated derivative....

On exposure to ammonia, LiBD4 and Mg(BD4)2 form the respective ammoniates, Li(11)BD4(ND3)n and Mg((11)BD4)2(ND3)6. We have identified the decomposition temperatures, kinetics...

The development of high energy density and high efficiency hydrogen storage materials is widely considered to be one of the most challenging barriers to the adoption of fuel...

The aim of this proposal is to determine that materials that are present in the ammoniation of amides.

We ask for 7 days on IRIS to study the quasielastic scattering in ammonium borohydride (NH4BH4). Using enriched ND4 and BD4, we aim to separate out the difference rotational and...

We request 3 days on HRPD with the IGAn apparatus, to perform in-situ neutron diffraction and thermogravimetric studies of the decomposition of deuterated alkaline amidoboranes....

Ammonia borane (AB) is a promising hydrogen storage material with up to 12 wt% obtainable from 100 to 150 C. Desorption temperatures can be lowered towards targets and kinetics...

This proposed experiment is a muon spin rotation measurement of the hyperfine transition rate in muonic atoms involving a proton or deuteron. The residual spin polarization of a...

We request 9 days on TOSCA to study (i) the interaction of adsorbed H2 gas molecules with a gated indium-based metal-organic framework (MOF) NOTT-200 as a function of H2 and...

Hydrogen storage is considered to be one of the principal technological barriers in the transition towards a hydrogen-based economy. In this proposal, we plan to look at the key...

We ask for 4 days beam time on GEM to study the dehydrogenation and subsequent rehydrogenation of Mg(11BD4)2. Mg(BH4)2 is currently one of the most promising lightweight...

Hydrogen storage is one of the most important technological issues to be resolved in the move towards a future sustainable hydrogen-based economy. We would like to gain further...

Despite the large research effort that has been made, the microscopic processes of hydrogen chemisorption on graphite is not well understood. By ball milling graphite for a...

On exposure to ammonia, Li(11)BD4 forms the ammoniate Li(11)BD4(ND3)n. Our recent experiment (RB820252) has shown that there are four distinct crystalline phases in the...

The development of high energy density and high efficiency hydrogen storage materials is widely considered to be one of the most challenging barriers to the adoption of fuel...

We request 4 days on HRPD with the IGAn apparatus to follow the structural changes of Me-ND4 11BD4 as a function of temperature. The high resolution of HRPD will allow us to...