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Effect of alloying on the misfit of Ni-Ni3Al-Ni3V alloys
The exceptional high temperature mechanical properties of Ni-base superalloys has resulted in their widespread use in high temperature applications. These alloys conventionally... -
HIGH RESOLUTION NEUTRON DIFFRACTION STUDIES ON NEW POLYMORPHS OF MAGENSIUM TE...
The development of high energy density and high efficiency hydrogen storage materials is widely considered to be one of the most challenging barriers to the adoption of fuel... -
Structure of Molecular Hydrogen in Synthetic Laponite Clay Hydrates
In this proposal we aim to study low temperature structure of hydrogen in the interlayer region of partially hydrated pillared clays. There are linked dual motivations for this... -
Measurement of residual polarization and hyperfine transition rate in muonic ...
This proposed experiment is a muon spin rotation measurement of the hyperfine transition rate in muonic atoms involving a proton or deuteron. The residual spin polarization of a... -
Direct measurement of the Au-D bond
Gold is historically thought of as an inert metal, and so investigation of its chemistry has been under-investigated. In 1986 it was shown that gold can be incredibly active as... -
Spatial, Chemical, and Temporal Resolution of Platinum-Catalysed Benzene Conv...
This proposal aims to study the potential for neutron diffraction to offer spatially-, chemically-, and temporally-resolved information on a dynamic system, in this case the... -
Hydrogenation of Benzene followed by Total Scattering and in situ 13C NMR
Catalysis is defined as the increase of the rate of the reaction or directing the reaction to one of the thermodynamically permitted pathways that lead to different products. It... -
IN-SITU INELASTIC NEUTRON SPECTGROSCOPY STUDIES OF METAL-HYDRIDE HYDROGEN STO...
Hydrogen storage is considered to be one of the principal technological barriers in the transition towards a hydrogen-based economy. In this proposal, we plan to look at the key... -
Reversible Redox in a Cerium (IV) Germanate Scheelite: a New Oxygen Storage M...
Materials that show oxide-ion mobility (solid electrolytes) and/or reversible uptake and release of oxygen (oxygen storage materials) have important uses in applications... -
Probing the Kinetics and Liquid Structure of Toluene Hydrogenation by Pt/MCM-41
In a proof-of-concept beamtime award (RB1220486) we studied the process of platinum-catalysed benzene hydrogenation in the pores of MCM-41 using standard neutron diffraction... -
Vibrational properties of Vanadium and Zirconium based metal hydrides
Inelastic neutron scattering has proven to be reliable tool to investigate the phonon structure of hydrides. E.g., it was shown that the vibrational structure of Ca(BH4)2 has a... -
In-situ study of hydrogen absorption and desorption in metal-hydride hydrogen...
Hydrogen storage is one of the most important technological issues to be resolved in the move towards a future sustainable hydrogen-based economy. We would like to gain further... -
Hydrogen bonding in amorphous formic acid
Formic Acid (FA) is a simple model for rotational isomerism, and it presents four different hydrogen bonding sites. In a recent study, we have elucidated the structure of FA in... -
Polymer electrolyte morphology investigated by SANS
Polymer electrolytes constitute a promising class of materials for rechargeable Li-batteries. The ionic conductivity behavior is dependent on the local morphology of the... -
A study of hole injection efficiency for a model conjugated bilayer system
Polymer-based electronics have attracted huge interest due to their wide applicability to light emitting diodes, field effect transistors and photovoltaics. The aim of our... -
Interaction of Chiral Amino Acids with Hydrated Vermiculite Clay
The aim of this proposal is to obtain an atomistic understanding of the adsorption of chiral amino acids on mineral surfaces. Our previous experiments on LOQ and at ILL on D16... -
Neutron Diffraction Studies on Double-Hydrogen-Bridged Diborane(4) Compound
The object of the proposed experiment is to definitively locate hydrogen atoms on the extraordinary short B¿B bond by single crystal neutron diffraction method. Because the... -
In situ Investigation of the Locations of Gas Molecules within a Decorated Po...
In the coming year, we plan to build upon the success of last cycle by carrying out more hydrocarbon studies of this porous material NOTT-300 and one of its iso-structural... -
Neutron Total Scattering Studies on Disordered Hydrogen Storage Material Na2B...
We aim to use total scattering and pair distribution function (PDF) analysis to determine the local structure of the disordered amide-borohydride, Na2BH4NH2. We wish to... -
Diffusion of molecular hydrogen into pre-formed THF clathrate hydrate
The proposing team has a well established experience in the use of neutron scattering on samples containing molecular hydrogen, and has recently studied some aspects of the...