Probing the Kinetics and Liquid Structure of Toluene Hydrogenation by Pt/MCM-41

DOI

In a proof-of-concept beamtime award (RB1220486) we studied the process of platinum-catalysed benzene hydrogenation in the pores of MCM-41 using standard neutron diffraction techniques on NIMROD. Our results have shown that following such reactions in a time-resolved manner is feasible (at suitable temperature and pressure conditions), and initial data indicates a clear two-step hydrogenation process. A full analysis of this data is underway. We intend to continue to probe the capabilities of the method by studying toluene hydrogenation in situ within the same catalyst. This system offers a different set of challenges, since the product distribution potentially consists of a number of isomers (while the benzene reaction did not). Again, we will complement the neutron scattering results with parallel NMR studies of the reaction.

Identifier
DOI https://doi.org/10.5286/ISIS.E.24090634
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/24090634
Provenance
Creator Dr Lyn Gladden; Dr Daniel Bowron; Dr Tristan Youngs; Professor Chris Hardacre; Miss Hannah Dunckley; Professor Jim Anderson; Dr Johannes Kiefer; Dr Manish Pratap Singh; Miss Claire Boudie
Publisher ISIS Neutron and Muon Source
Publication Year 2016
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Photon- and Neutron Geosciences
Temporal Coverage Begin 2013-05-13T23:00:00Z
Temporal Coverage End 2013-06-10T07:09:48Z