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Heterolytic Cleavage of H2 using Non-Metal Frustrated Lewis Pairs
The synthesis of Frustrated Lewis Pairs (FLP¿s) have recently experienced a huge surge in popularity as they have been found to be a novel approach for the activation of small... -
Structure-property relationships in new oxide ion conductor Ba3NbWO8.5
Oxide ion conductors have been a focus of intense research due to their application as electrolytes in solid oxide fuel cells. The currently used materials (yttria-stabilised... -
High pressure behaviour of ammonium carbonate monohydrate
A number of compounds crystallise in the NH3-H2O-CO2 ternary system, including ammonium carbonates and carbamates, these being closely related to the water-deficient compound... -
Short range magnetic correlations in Gd3Ga5O12
In recent years topologically complex materials have provoked questions about the basic models of magnetism. These materials have given rise to unusual phenomena, including... -
X-ray Radiation damage to DNA at the atomic level
The interaction of ionizing radiation such as X-rays with biological samples causes damage to the samples. Recent work from our group with various protein crystals, peptides and... -
Compression of meridianiite (MgSO4.11D2O) single crystals to 5 kbar
We propose to carry out single crystal diffraction measurements of the most hydrated MgSO4 compounds, meridianiite, using a thin-walled TiZr gas cell on SXD up to 5 kbar. These... -
Single-crystal analysis of disorder in deuterated and protonated mirabilite
Mirabilite (Na2SO4.10H2O) is relevant to many areas of geology, planetary science, and even the construction industry. It occurs naturally in evaporite deposits, and even as... -
ZIF-4 SC-Diffraction
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Determination of the configurational stability of organosamarium intermediate...
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Neutron Diffraction Studies on YbCu4Ga8
We discovered a new compound YbCu4Ga8 and the available laboratory single crystal data shows that it crystallizes in the tetragonal system. The asymmetric unit contains one Yb... -
Crystal structure of mallardite, manganese sulfate heptahydrate
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Structure of TEA(TCNQ)2
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Cation substitution in synthetic meridianiite (MgSO4.11H2O): site distributio...
MgSO4.11H2O (MS11) is the most highly hydrated phase in the binary MgSO4¿H2O system. Whilst lower hydrates in this system have end-member analogues containing alternative... -
Structural characterization of a fully detuterated manganese Prussian Blue an...
The aim of this proposal is to perform a neutron diffraction determination of the first perdeuterated Mn-Prussian Blue (PB) analogue of composition: Mn(II)3 [Mn(III)(CN)6]2... -
Elucidating the Structure of [(LaCl)Ti28O40(OEt)38(X)]; but what is X?
Metal-doped TiO2 have particular applications as in catalysis of a range of reactions as well as in luminescence materials. Our strategy is to make well-defined molecular TixOy... -
Single-Crystal Neutron Diffraction Study on [U(C5Me5)2(H)(mu¿H)]2
To our knowledge, the length of the U¿H single bond has never been accurately measured, at least not in a molecular compound by single-crystal neutron diffraction. We currently... -
Investigating the origin of thermochromism in N-salicylideneanilines
Anils, N-salicylideneanilines, display thermochromism, which is thought to involve an intramolecular proton shift, but to-date the structural changes postulated to occur during... -
Determination of the crystal structure of CsNiCl3 and RbNiCl3 under hydrostat...
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Proton ordering and hydrogen bonding in the hydrous zinc phosphate hopeite, Z...
We request 4 days of beamtime on SXD in order to locate the protons and quantify their ordering within the structure of hopeite Zn3(PO4)2.4H2O. Hopeite is an important phase in... -
Multitemperature measurements of 2,6-diaminopurine monohydrate crystals
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