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Phonon-Liquid-Electron Crystal Behaviour in Cu8GeSe6
Thermoelectric devices enable the conversion of thermal energy into electrical power. The development of new materials is essential to enable large scale implementation of... -
Cation Ordering in Quaternary Sulphides and Selenides
We wish to investigate quaternary chalcogenides, A2ZnBQ4 (where A = Cu, Ag; B = Ge, Sn; Q = S, Se). Calculations indicate stannite (S) or kesterite (K) superstructures of both... -
Development of a Novel Low - Intermediate Temperature Solid Proton Conductor
The compound, Si5O(PO4)6, is a component of a solid phosphoric acid catalyst, it has highly unusual coordination of the silicon (octahedral, as well as the more common... -
Phase Transitons and Phonon-Liquid-Electron Crystal Behaviour in Argyrodites
We wish to collect powder neutron diffraction as a function of temperature on four samples of argyrodites, A8GeQ6 (A = Cu, Ag; Q = S, Se), to investigate structural phase... -
Influence of shear on polymer adsorption at solid / liquid interfaces
Lubricants contain a complex mixtures of polymers and base oils that must provide protection to moving surfaces with minimal energy loss due to friction or viscous drag. There... -
Structural and magnetic characterisation of polar magnetic perovskite-based m...
A new generation of low-power high-density information storage would be enabled by the development of ?multiferroic? materials which function at or above room temperature. Such... -
Structural Phase Diagram of the new Multiferroic Hexagonal YbFeO3
This experiment aims to map out the structural phase diagram of the new multiferroic compound hexagonal-YbFeO3 as a function of temperature, both above and below room... -
Towards an accurate structural phase diagram for the novel BiScO3-PbTiO3 ferr...
The aim of this experiment is to determine accurately the crystal structures of phases in the (1-x)BiScO3-xPbTiO3 (BST-PT) perovskite phase diagram, particularly in the vicinity... -
Matrix Effects on Polymer Surface Segregation
We have used neutron reflectivity and complementary techniques of ion beam analysis and contact angle to understand the adsorption behaviour of multi-fluoro end functional... -
Anion disorder in Ti pyrochlores as a precursor in the transition to fluorite
The aim of this work is to understand the nature of anion disordering in pyrochlore oxides and to establish what, if any, correlations exist between the anion position, disorder... -
Hydrogen Release Systems: MX2.(NH3)n (M=Mg, X=Cl) with LiH and MgH2
The applicants seek 3 days of beam time on POLARIS to study hydrogen release systems comprising M(NH3)6X2 (M=Mg, X=Cl) coupled with LiH and MgH. Mg(NH3)6Cl2 is an important... -
Deammoniation Investigations of the ammines MX2.nNH3 (M= Mg, X= I,Cl,Br)- pot...
The applicants seek 4 days of beam time on POLARIS to study the deammoniation process of synthesised M(NH3)6X2 (M=Mg, X=I, Cl, Br) which are an important class of materials for... -
The origin of high oxide-ion conductivity and the nature of the intermediate ...
4 days of beam time is requested on HRPD to study the crystal chemistry of the ferroelectric Aurivillius phase Bi4Ti3O12 (Curie Temperature, Tc ~ 675 C, mixed conductor) and a... -
VT studies of the local structure of a fuel cell cathode and lead-free ferroe...
We are about to submit a detailed pair distribution function study of a new lead-free ferroelectric material based on RMC analysis. This method will be applied in VT studies of... -
Structure and encapsulation of additives in spray coated surfactant templated...
This proposal continues our work into surfactant templated films formed from surfactant/polyelectrolyte solutions. Recently we have been studying the encapsulation of...
