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The Effect of Hydrogen Bonding on the Nucleophilicity and Basicity of Fluorid...
In nucleophilic fluorination reactions it is extremely difficult to tune the reactivity of the fluoride anion in organic solution to give the desired product. Building on our... -
The Crossover Between Giant Magnetoresistance and Superconductivity in RuSr2G...
Giant magnetoresistance (GMR) is observed up to -49% in RuSr2R1.8-xY0.2CexCu2O10-d ruthenocuprates. The magnetotransport is very sensitive to lattice effects. As , the mean A... -
The Dynamics of Molecular Hydrogen in Synthetic Na-Laponite
In this proposal we aim to study the low temperature uptake and dynamics of hydrogen in the interlayer region of partially hydrated pillared Na-laponite clay. There are linked... -
The interaction of hydrogen with gallium oxide
There is an increasing interest in the application of gallium oxide as a catalyst support material, with particular interest in its use in new methanol steam reforming... -
The Formation of Ion Channels in Phospholipid Bilayers by Puroindoline-a
Puroindolines are basic, cysteine rich proteins of ~13KDa, which have attracted significant interest due to their role in determining the endosperm texture of Wheat and seed... -
The anisotropy of the spin fluctuations in the electron nematic phase of Sr3R...
New electronic phases often emerge in the proximity of a quantum critical point (QCP) - that is the point where the transition temperature of a collective phase transition is... -
The effect of Sn and Oxygen on the deformation mechanisms in Zirconium
The aim of this experiment is to study the effect of Sn and Oxygen on deformation mechanisms in Zr alloys with a particular emphasis on studying twinning. Both alloying elements... -
The interpenetration of two poly(ethylene oxide) polymer brushes under confin...
Coating two surfaces with polymer brushes has been shown on many occasions to reduce friction by orders of magnitude. These ultra-low frictions are believed to stem from be the... -
Interaction of a small protein with water and other solutes: The case of Glut...
The tripeptide glutathione (GSH) is present in cells at millimolar concentrations, and the ratio of GSH to glutathione disulfide (GSSG) is critical to cellular redox balance.... -
The effect of a vanishing pseudogap on the magnetic excitations in overdoped ...
One of the major issues in high temperature superconductivity is the nature of the so called pseudogap phase. A related question is whether the pseudogap controls the evolution... -
The effect of aluminium on the deformation mechanisms in titanium alloys
The aim of this experiment is to measure the intergranular strain evolution in two types of single phase titanium alloys. While commercially pure titanium (CP-Ti) is known to... -
The structure of biomimetic helices in aqueous solutions
Protein secondary structure, in particular alpha-helical structure, is essential for a variety of functions in nature. These structures are integral to such biophysical... -
The effect of γ′ particle size on the γ/γ′ load tr...
The aim of this experiment is to measure the load transfer between the matrix and the precipitates in an advanced nickel¿base superalloy as a function of particle size... -
The role of Bi in magnetic and structural dimerization of Ba3BiRu2O9.
The aim of the present proposal is to use total scattering to investigate changes in the local structure of Ba3BiRu2O9. This compound undergoes an unusual magnetovolume... -
The Neutron Scattering Spin Resonance: A probe of the momentum structure of t...
We propose to use MERLIN to examine the full magnetic excitation spectrum Chi¿(q,w) of optimally doped Fe based superconductor BaFe1.84Co0.16As2. The primary goal of this... -
Kagome quantum spin liquids - The case of Vesignieite
We aim to explore the groundstate of a new near-perfect S=1/2 kagome antiferromagnetic (KAFM) system using MuSR at the lowest possible temperatures. The title compound is... -
The effect of dendrimer surface functionalization on the interaction with mod...
Dendrimers are a unique class of nano-structured vehicles for drug and gene delivery into intracellular targets. Their surface chemistry influences their transport across... -
Fundamentals of Nanotoxicity: The Role of Nanoparticles in Lowering the Energ...
Despite the increasing use of nanoparticles (NPs), our current knowledge of how NPs interact with the human body or the environment remains limited. Of a number of mechanisms, a... -
The role of dislocation slip on the activation of different twinning modes in...
Twinning is an important deformation mechanism in hcp metals like Zirconium. It is now accepted that, unless twinning is accounted for, the typical deformation textures in these... -
The search for long range exchange interactions in the S=1 square lattice ant...
Exchange interactions in insulators can be understood in terms of the Andersen exchange picture in which the Hamiltonian has two contributions: (i) a kinetic term characterized...